Delocalization Engineering of Heme‐Mimetic Artificial Enzymes for Augmented Reactive Oxygen Catalysis
Qian Li,
Zhenyang Zhao,
Fan Chen
et al.
Abstract:Developing artificial enzymes based on organic molecules or polymers for reactive oxygen species (ROS)‐related catalysis has broad applicability. Herein, inspired by porphyrin‐based heme mimics, we report the synthesis of polyphthalocyanine‐based conjugated polymers (Fe‐PPc‐AE) as a new porphyrin‐evolving structure to serve as efficient and versatile artificial enzymes for augmented reactive oxygen catalysis. Owing to the structural advantages, such as enhanced π‐conjugation networks and π‐electron delocalizat… Show more
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