Densities and Volumetric Properties of Binary Mixtures of Butyl Acrylate with Benzene, Toluene, o-Xylene, m-Xylene, p-Xylene, and Mesitylene at Temperatures from 288.15 K to 318.15 K

Abstract

The densities, ρ, of binary mixtures of butyl acrylate (BA) with benzene, toluene, o-xylene, m-xylene, p-xylene, and mesitylene, including those of pure liquids, over the entire composition range were measured at the temperatures (288.15, 293.15, 298.15, 303.15, 308.15, 313.15, and 318.15) K and atmospheric pressure. From the experimental data, the excess molar volumes, V E m were calculated. The V E m values were negative over the whole composition range for all the mixtures and at each temperature studied, except for BA + mesitylene which exhibit positive V E m values, indicating the presence of specific interactions between BA and aromatic hydrocarbon molecules. The deviations in V E m values follow the order: benzene < toluene < p-xylene < m-xylene < o-xylene < mesitylene. It is observed that V E m values depend upon the number and position of the methyl groups in these aromatic hydrocarbons.

Density and Surface Tension of Binary Mixtures of 2,2,4-Trimethylpentane + n-Heptane, 2,2,4-Trimethylpentane + n-Octane, Ethyl Acetate + Benzene, and Butanenitrile + Benzene from (293.15 to 323.15) K

“… a Standard uncertainty in the density measurement = 3·10 –2 kg·m –3 , standard uncertainty in the surface tension = 0.03 mN·m –1 , and standard uncertainty in the temperature measurement = 0.01 K. a Reference . b Reference . c Reference . d Reference . e Reference . f Reference . g Reference . h Reference . i Reference . j Reference . k Reference . l Reference . m Reference . n Reference . o Reference . p Reference . q Reference . r Reference . s Reference . t Reference . u Reference . v Reference . w Reference . x Reference . y Reference . z Reference . aa Reference . ab Reference . ac Reference . ad Reference . ae Reference . af Reference . ag Reference . ah Reference . ai Reference . aj Reference . …”

Density, partial, and excess volumes of solutions of methacrylic acid in organic solvents at 293 K

“…A great many works on determining the density and excess molar volumes of solutions of acrylic and meth acrylic acids and their ethers have been published to date [1][2][3][4][5][6]. Many systems have yet to be studied by researchers, however, despite their great interest in solutions of compounds of the acrylic series.…”

Generalized equation of state for the cyclic hydrocarbons over a temperature range from the triple point to 700 K with pressures up to 100 MPa

“…Willingham et al [21] Forziati et al [22] Dreyer et al [102] Buscharz et al [104] Muthu et al [105] Denisov et al [106] Gregorowicz et al [107] Anderko [108] Cepeda et al [109] Pressure, MPa AAD, % Cibulka et al [11] Moravkova et al [126] Resa et al [127] Al-Kandary et al [45] Nain et al [128] Gonzalez-Olmos et al [115] Nain et al [129] Burmistrov et al [123] Aminabhavi et al [124] Aralaguppi et al [125] Fig. B.16…”