Density and speed of sound of 2-chloropropane in the range of temperatures 293.15–373.15 K and pressures up to 196.2 MPa

Melent'ev, Vyacheslav V.; Postnikov, Eugene B.

doi:10.1016/j.cdc.2019.100270

Cited by 3 publications

(1 citation statement)

References 17 publications

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“…where ρ 0 and κ T 0 are the densities and the isothermal compressibilities at normal pressure, respectively, and k is the local slope of the tangent to the function ln(ρκ T ), whose derivation is explained in details elsewhere. 2,22 Here we only mention that it follows from the almost exponential dependence of the inverse reduced density fluctuation parameter on density at the saturation conditions:…”

Section: ■ Modeling and Discussionmentioning

confidence: 99%

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Melent'ev¹,

Postnikov²,

Polishuk

2018

Ind. Eng. Chem. Res.

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This study reports the experimental density and speed of sound data of 1-chlorononane along seven isotherms from 293.15 to 413.15 K at pressures from saturation up to 196.1 MPa. The pertinent isothermal compressibility and isobaric coefficient of expansion data have been obtained by numerical differentiating of densities. In addition, the saturated liquid densities have been measured from 253.15 to 443.15 K, isobaric heat capacities from 248.15 to 448.15 K, and speeds of sound from 246.88 to 457.25 K. These results have been interpolated by polynomials to obtain the saturated liquid isobaric coefficient of expansion, adiabatic and isothermal compressibility, isochoric heat capacity, and internal pressure data. Performances of three predictive approaches having different degrees of complexity, namely the Critical Point-based Perturbed Chain Statistical Association Fluid Theory, the Statistical Association Fluid Theory of Variable Range Mie Potential parametrized by a Corresponding States approach of Mejía et al. (Ind. Eng. Chem. Res. 2014, 53, 4131), and the fluctuation theory-based Tait-like equation of state have been examined. The latter model has a superiority in estimating of the high-pressure data; however, unlike both statistical association fluid theory approaches, it utilizes the saturated liquid data. It has also been demonstrated that all the models successfully predict various phenomena related with replacement of hydrogen by chlorine in n-nonane molecule.

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Section: ■ Modeling and Discussionmentioning

confidence: 99%

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Melent'ev¹,

Postnikov²,

Polishuk

2018

Ind. Eng. Chem. Res.

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Direct and inverse problem of interrelation between the high pressure and the density: The case study of liquid bromobenzene's acoustic sounding

Verveyko,

Belenkov,

Postnikov

2024

Applied Acoustics

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Thermophysical properties of chloropropanes in liquid phase: Experiments and simulations

Jasiok

Chorążewski

Pribylov

et al. 2022

Journal of Molecular Liquids

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Density and speed of sound of 2-chloropropane in the range of temperatures 293.15–373.15 K and pressures up to 196.2 MPa

Cited by 3 publications

References 17 publications

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Direct and inverse problem of interrelation between the high pressure and the density: The case study of liquid bromobenzene's acoustic sounding

Thermophysical properties of chloropropanes in liquid phase: Experiments and simulations

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Density and speed of sound of 2-chloropropane in the range of temperatures 293.15–373.15 K and pressures up to 196.2 MPa

Cited by 3 publications

References 17 publications

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Experimental Determination and Modeling Thermophysical Properties of 1-Chlorononane in a Wide Range of Conditions: Is It Possible To Predict a Contribution of Chlorine Atom?

Direct and inverse problem of interrelation between the high pressure and the density: The case study of liquid bromobenzene's acoustic sounding

Thermophysical properties of chloropropanes in liquid phase: Experiments and simulations

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Density and speed of sound of 2-chloropropane in the range of temperatures 293.15–373.15 K and pressures up to 196.2 MPa