An 11-yr (1990-2001) time series of tritium-helium-3 ( 3 H-3 He) apparent water ages as well as one sulfur hexafluoride (SF 6 ) profile were used to study the development of the vertical mixing dynamics of the deep, meromictic northern basin of Lake Lugano. The density stratification of the water column was dominated by an increase in dissolved ions with depth, which remained approximately constant during the 1990s. The deep-water temperature increased steadily during this period, passing a threshold above which cooling of the surface water could force convection. However, increasingly mild winter temperatures prevented the occurrence of a turnover until 2005. The maximum apparent 3 H-3 He water age increased from about 16 yr in 1990 to 23 yr in 2001. The maximum apparent SF 6 age in 2001 was 12.8 yr. The large difference between the apparent 3 H-3 He and SF 6 ages is at least partly due to nonlinear effects of mixing, causing SF 6 ages to underestimate the true mean deep-water residence time, whereas 3 H-3 He ages overestimate it. The decreasing concentrations of 3 H and 3 He are more reliable indicators of the continuous deep-water exchange in the lake than are the apparent ages. Budget calculations using the tracer concentrations reveal an annual renewal of the deep water below 100 m in depth by about 8% and enable the calculation of long-term mean profiles of the effective vertical turbulent diffusivity K z . No trend in the mixing intensity during the 1990s could be determined. The radiogenic He flux into the lake is comparable to estimates of the whole crustal degassing flux. Lake Lugano is a deep perialpine lake, which, as a result of eutrophication during the second half of the last century, experienced a serious deterioration of water quality, in particular a complete and enduring anoxia in the deep water below about 100 m in depth (Barbieri and Mosello 1992). Although the inflow of nutrients has been reduced and the water quality of the surface water has improved during the last decades, the regeneration of the deep water body has been a very slow process, impaired by sluggish vertical mixing due to a chemical stratification of the water column (Wü est et al. 1992). A thorough understanding of the mixing dynamics of the lake, including the response to changing biogeochemical and climatic conditions, is therefore important for the management of the lake.Transient environmental tracers such as the tritiumhelium-3 ( 3 H-3 He) isotope pair or chlorofluorocarbons (CFCs) have proved to be excellent tools for studying the mixing dynamics of lakes (e.g., Torgersen et al. 1977;Weiss et al. 1991;Aeschbach-Hertig et al. 1996). The methods are
AcknowledgmentsWe thank Urs Beyerle, Matthias Brennwald, Roland Hohmann, David Livingstone, and Frank Peeters for their respective contributions to the fieldwork, the He and 3 H analyses, the preparation of the CTD data, and the improvement of the manuscript. Special thanks go to Dieter Imboden and Alfred Johny Wü est for support and advice in the early phase of the...