Density, Excess Molar Volume, and Viscosity for the Methyl Methacrylate + 1-Butyl-3-methylimidazolium Hexafluorophosphate Ionic Liquid Binary System at Atmospheric Pressure

Abstract

Densities and viscosities for the methyl methacrylate (MMA) and 1-butyl-3-methylimidazolium hexafluorophosphate ([BMIM][PF6]) ionic liquid binary system, over the whole concentration range in the temperature range from (283.15 to 353.15) K, were measured by using an Anton Paar DMA 5000 densimeter and an Anton Paar AMVn Measuring Assembly, respectively. The excess molar volumes V E were calculated by using the measured experimental densities and correlated by the Redlich−Kister type equation. The correlation results are in good agreement with the experimental data, and optimal fitting parameters are present. All the V E values within the scope of research are negative and become more and more negative with increasing temperature.

Density, Refractive Index, Apparent Volumes and Excess Molar Volumes of Four Protic Ionic Liquids + Water at T=298.15 and 323.15 K

“…The data for excess molar volume were correlated by the Redlich-Kister equation (Fan et al 2008;Fan et al, 2009;Kurnia and Mutalib, 2011;Patil et al, 2011).…”

Green process for methacrolein separation with ionic liquids in the production of methyl methacrylate

“…The absorbent is a mixture of BmimBF 4 and methanol, considering that the addition of methanol can largely decrease the viscosity 31 and methanol is also a reactant for the next reaction, which does not need to be separated. In this process, the separation process of MAL is further simplified, because only one column was used and no compressor was needed.…”

Cation and anion dynamics in supercooled and glassy states of the ionic liquid 1-butyl-3-methylimidazolium hexafluorophosphate: Results from13C,31P, andEndo1, Widgeon2, Yu3 et al. 2012Phys. Rev. B230150View full textAdd to dashboardCite

“…(b) The reported relaxation times shown in Fig. 10a (gray), τ vis estimated from the viscosity data 34,71 when G ∞ = 10 8 and the VFT fit (black), relaxation times τ DLS from depolarized light scattering study by Rivera et al 19 (red squares) and the relaxation times τ cation (green, purple and orange symbols, see …”