No-Core Gamow Shell Model (NCGSM) is applied for the first time to study selected well-bound and unbound states of helium isotopes. This model is formulated on the complex energy plane and, by using a complete Berggren ensemble, treats bound, resonant, and scattering states on equal footing. We use the Density Matrix Renormalization Group method to solve the manybody Schrödinger equation. To test the validity of our approach, we benchmarked the NCGSM results against Faddeev and Faddeev-Yakubovsky exact calculations for 3 H and 4 He nuclei. We also performed ab initio NCGSM calculations for the unstable nucleus 5 He and determined the ground state energy and decay width, starting from a realistic N 3 LO chiral interaction.