Abstract. We consider the problem of impurity states in the vicinity of Dirac point in graphene taking into account the spin-orbit (SO) interaction. Two main contributions to the SO interaction, namely the internal and Rashba, are considered. Even though the internal SO interaction is relatively small, its effect is crucial because a very small perturbation potential can create both discrete and resonance impurity states located near the gap. In the case of strong Rashba SO interaction like in the case of graphene on a substrate, the resonance impurity states can be created producing some anomalies in transport properties.
IntroductionElectric and magnetic properties of graphene are mostly determined by the electronic states in the vicinity of Dirac points [1,2,3,4,5]. If the spin-orbit (SO) interaction is neglected [7,8,9, 10], the energy spectrum in these points is degenerate, and the elementary excitations belong to the linear spectrum, which can be described by the two-dimensional relativistic Dirac model [6]. In reality, the SO interaction is not zero and, correspondingly, there is an energy gap [11]. However, it was found that in case of internal SO interaction the magnitude of SO gap is very small, and correspondingly it can be neglected [12,13,14,15]. In this paper we demonstrate that even though the energy gap is really very small, the presence of SO interaction of any origin leads to formation of additional low-energy impurity states, which are absent if the SO interaction is neglected. Besides, we find that the impurity creating very small perturbation like, for example, some neutral adatoms or molecules, can be responsible for these states.In the case of SO interaction related to the Rashba term, the magnitude of SO is not necessarily small, and the energy spectrum at low energies is completely different from the Dirac spectrum. In this case one can also study the problem of impurity states, which can be effectively controlled by electric gate, as it is known that the electric field of the gate modifies the magnitude of Rashba SO coupling.