Density of states within the bandgap of perovskite thin films studied using the moving grating technique

Abstract

In this work, we further study the moving grating technique applied to halide perovskite thin-film materials. Firstly, we show some problems that emerge when analyzing experimental data with the classical formulation, which does not distinguish between free and trapped carriers and hence only gives average quantities for the transport parameters. We show that using a more general framework, taking into account the multiple trapping of carriers within a density of localized states, allows an accurate description. Since it includes the density of state (DOS) of the material, it enables the possibility to test different DOS models proposed in the past for halide perovskite thin films. We check whether these models give rise to the type of curves we have measured under different experimental conditions. Finally, we propose a new model for the DOS in the forbidden gap, which results in the best fit found for the measurements performed. This allows us to give ranges of values for the parameters that define the DOS, which, as far as we know, are given for the first time.

Low-Temperature Emission Dynamics of Methylammonium Lead Bromide Hybrid Perovskite Thin Films at the Sub-Micrometer Scale

“…While methylammonium lead iodide (MAPI) has been arguably the most successful halide perovskite so far for application in solar cells [ 12 , 13 ], methylammonium lead bromide (MAPbBr ) thin films or single crystals find applications in LEDs, scintillation and photodetector devices [ 10 , 14 , 15 ]. The dynamics and origin of their emission have thus been the center of several studies and are still highly debated subjects [ 16 , 17 , 18 , 19 , 20 , 21 , 22 , 23 , 24 , 25 ]. In order to improve device quality, it is also important to understand the spatial dependence of their emission, i.e., performing not only ensemble measurements, but also spatially resolved experiments, at the micrometer scale [ 26 , 27 ].…”