2005
DOI: 10.1016/s0167-2991(05)80521-x
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Dependence between the activity and selectivity of NaLaY and NaCeY catalysts in the catalytic disproportionation of toluene

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Cited by 5 publications
(3 citation statements)
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“…The general composition of zeolites can be represented by M y/z [(SiO 2 ) x (AlO 2 ) y ]nH 2 O where M is the exchangeable ion metal with a valency z. Zeolites are a suitable choice as they have a large cation exchange capacity and an affinity for heavy metals [4][5][6][7][8][9]. They are widely used as sorbents [10][11][12][13][14], catalysts [15][16][17][18] and cation exchangers [19][20][21][22][23]. The NaX zeolite cations are located in the sodalite super cage and double hexagonal rings of the zeolite Taking into consideration these approaches, we focus our attention to the use of models based on Fick's laws in the analysis of experimentally obtained data, and to determine the step describing the mechanism of the reaction according to Eq.…”
Section: Introductionmentioning
confidence: 99%
“…The general composition of zeolites can be represented by M y/z [(SiO 2 ) x (AlO 2 ) y ]nH 2 O where M is the exchangeable ion metal with a valency z. Zeolites are a suitable choice as they have a large cation exchange capacity and an affinity for heavy metals [4][5][6][7][8][9]. They are widely used as sorbents [10][11][12][13][14], catalysts [15][16][17][18] and cation exchangers [19][20][21][22][23]. The NaX zeolite cations are located in the sodalite super cage and double hexagonal rings of the zeolite Taking into consideration these approaches, we focus our attention to the use of models based on Fick's laws in the analysis of experimentally obtained data, and to determine the step describing the mechanism of the reaction according to Eq.…”
Section: Introductionmentioning
confidence: 99%
“…Selon la litté rature [8,16,[18][19][20], la ré action de dismutation du toluè ne peut avoir lieu selon deux mé canismes possibles montré s par la Fig. 3.…”
Section: Re´action De Dismutation Du Tolue`neunclassified
“…The zeolite Y is of utmost importance in heterogeneous catalysis; for example, it is the active component in catalysts for fluid catalytic cracking [10][11]. Its porous system is relatively complicated and consists of spherical cages, referred to as supercages, with a diameter of 13 Å connected tetrahedrally with four neighbouring cages through windows with a diameter of 8 Å [12].…”
Section: Introductionmentioning
confidence: 99%