es, however, the increasingly sophisticated measurements are indispensable along with spin-polarization and correlation effects. Such spin studies have initially been on either electron-atom or atom-atom collision processes in order to investigate, for instance, the collision mechanism for spin-polarized electrons tracing the behavior of individual electrons or effects upon the trajectory [3] and the rotational couplings [4] with a collision-induced alignment of the final state. In contrast, owing to technical difhculties in producing and manipulating polarized atoms and ions, the electron-capture processes in ion-1185 atom collisions with spin-polarized partners have long been beyond our reach even though the theory analogous to the electron-atom system might be valid.Meanwhile, a novel idea for polarizing a proton beam using the electron-capture processes between an incident proton and a polarized alkaline atom was proposed [5,6] more than a decade ago and later employed as a practical polarized ion source [7] dedicated to nuclear physics research. The above idea recently succeeded in polarizing such heavier nuclei as He [8] and ' N [9]. Since the primary aim of the above capture processes has been restricted to practical use in polarized ion sources, theoretical investigation of the detailed collision mechanisms has not been attempted in spite of its physical importance.In the present paper we report on the polarization measurement and the theoretical understanding