This paper reports a new efficient solar selective surface in high temperature application. The influence of the monolayer's microstructure and deposition rate was firstly discussed. Then the nitride nano-multilayer on the polished stainless steel (herein after referred as "SS") substrate was prepared with Ti and Al metal targets by DC. and R.F. magnetron co-sputtering. The samples were annealed in air at different temperatures ranging from 350 to 800°C for 2 h to evaluate their thermal stability. The samples' surface and cross-section morphology, crystal structure, phase composition, optical properties were analyzed by scanning electron microscopy, X-ray diffraction, UV-VIS-NIR spectrophotometer and infrared emissivity tester. The results show that the coatings exhibit high solar selectivity (α/ε) of 0.943/0.08 even after heat-treatment up to 400°C for 2 h in air. After heat-treatment at 600°C in air, the solar selectivity decreases to 0.92/0.16. solar energy, nitride coatings, solar absorptance, thermal emittance, thermal degradation Citation: Hao L, Du M, Liu X P, et al. Thermal stability of nitride solar selective absorbing coatings used in high temperature parabolic trough current. SciThe main requirements for the solar selective absorbing coatings used in high temperature parabolic trough current solar collectors must have high absorptance α in the solar spectral range (0.3-2.5 μm) and low emittance ε in the infrared region (2.5-50 μm). It can convert low solar energy density to high heat energy density, enrich solar energy and improve the efficiency of photothermal conversion, which is an important content in field of solar energy heat utilization. The ideal characteristics of a photothermal converter is approximated by an absorber reflector tandem. The reflector is coated with a layer which is highly absorbing over the visible region and transparent in the infrared region. Generally, the absorbers degrade at high operating temperature because of unstable microstructure, which causes a decrease in the solar selectivity.Based on the different of sunlight absorption and coatings' structure, the selective absorbing coatings are divided into different basic types, such as semiconductor coating, optical interference coating, multi-graded coating, metalceramic coating and porous coating. To obtain the spectral selectivity various concepts have been studied such as cermet coatings, absorber-reflector tandem and multilayer absorber. A large number of high temperature solar selective coatings have been studied such as M-Al 2 O 3 (M=Pt, Ni, Mo, Cu) cermets, M-AlN (M=W, Mo, stainless steel) cermets, etc. The metal-ceramic composite coating has good thermal stability, and it is mainly used in high-temperature fields. It is a newly developed coating in recent years. Cermet is the incorporation of metal particles and nitrides or oxides medium. Because of the transition zone of metals and the resonance of small particles, this coating has strong absorption of solar spectrum. Common metal particles are Cu, Au,