The breakthrough of bauxite natural gas in the Taiyuan Formation in the Longdong area of the Ordos Basin makes bauxite natural gas gradually become a new exploration direction. However, the complex sedimentary conditions and diverse developmental strata of the Linxing region present difficulties for the exploration of bauxite gas. In this research, samples of bauxite cores from significant drilling sections in the Linxing area were obtained for comprehensive geochemical, mineralogical, and pore structure analysis. This study investigates the impact of sedimentary environments on the physical properties of bauxite reservoirs within the Benxi Formation, focusing on lithofacies categorization, mineral composition, and pore structure. This study established a lithofacies categorization system that iron minerals, aluminum minerals + titanium minerals, clay minerals as three end‐member components. The study identified four lithofacies types: pure bauxite, clayey bauxite, mixed bauxite, and bauxite mudstone. According to geochemical analysis, the bauxite rock in the study area is deposited in a semi‐enclosed bay with terrestrial freshwater input. The physical properties of bauxite reservoir in the study area are relatively poor, among which the physical properties of bauxite reservoir are the best. Authigenic minerals like pyrite are often filled in dissolution pores. The constraint of sedimentary environment on bauxite reservoir is mainly manifested as the influence on the formation of diaspore mineral framework, and its acidity and alkalinity are very important for the formation of diaspore. Hence, diaspore commonly forms in the shallow lake environments characterized by pure bauxite rock, exhibiting favorable reservoir conditions. This research examines the impact of mineral composition on bauxite reservoirs through the lens of lithofacies and sedimentary environments. The variations in bauxite rock reservoirs across distinct sedimentary environments have been elucidated. It provides a new guidance for the exploration of natural gas in Benxi Formation bauxite in Ordos Basin.