Derivation of a general theory for reversible multistep electrode processes in voltammetry with constant potential at spherical electrodes

Theoretical background for the behavior of molecules containing multiple interacting or noninteracting redox centers in any multipotential step technique and cyclic voltammetry

“…For an electrode process which implies the reduction of soluble molecules containing multiple redox centers (see Scheme 1 in Appendix A), the application of the superposition principle [12] allows the results previously obtained by us for one [13] and two [14] potential pulses applied to be generalized to any sequence of consecutive potential steps designed (E 1 ,E 2 , . .…”

Mathematical Modelling of the Electrode Process of Azithromycin Using Cyclic Voltammetry at Hanging Mercury Drop Electrode

“…[1][2][3][4][5] Interest in the electrochemical behaviour of active drug constituents has also been steadily increasing. [6][7][8] Investigation of electrode processes involving oxidation or reduction reactions may shed more light on in-vivo redox processes. 9,10 Several researchers have studied the kinetics of electrode processes pertaining to macrolide antibiotics under idealized experimental conditions.…”

Simulation of square wave voltammetry of three electrode reactions coupled by two reversible chemical reactions

“…Multistep electrode processes appear in electrochemistry of many organic compounds [1][2][3][4][5][6][7][8][9]. Some of these mechanisms include chemical steps [10][11][12][13][14][15].…”