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Cycles of wetting and drying can change the microstructure of vegetable fibers through a mechanism known as hornification, which modifies the polymeric structure of the fiber-cells resulting in a higher dimensional stability. In the present work the influence of hornification on the sisal fiber-matrix bond adhesion as well as in the sisal fiber dimensional stability and mechanical behaviour under direct tension was evaluated. Furthermore, cementitious composites reinforced with randomly dispersed hornified sisal fibers were developed and characterized under bending loads. The results show that the tensile strength and strain at failure of the hornified sisal fibers were increased by about 5% and 39%, respectively, whereas the modulus of elasticity was reduced by 9%. The fibers also presented higher dimensional stability with the hornification process. The fiber-matrix bonding was improved and the pull-out resistance of the fibers submitted to ten cycles of wetting and drying was increased by about 40% to 50%. The higher fiber-matrix bond strength contributed to an increase in the ductility and post-cracking behaviour of the composite. The fracture process was characterized by the formation of multiple cracks with the hornified sisal fibers presenting a higher ability to bridge and arrest the cracks.
Cycles of wetting and drying can change the microstructure of vegetable fibers through a mechanism known as hornification, which modifies the polymeric structure of the fiber-cells resulting in a higher dimensional stability. In the present work the influence of hornification on the sisal fiber-matrix bond adhesion as well as in the sisal fiber dimensional stability and mechanical behaviour under direct tension was evaluated. Furthermore, cementitious composites reinforced with randomly dispersed hornified sisal fibers were developed and characterized under bending loads. The results show that the tensile strength and strain at failure of the hornified sisal fibers were increased by about 5% and 39%, respectively, whereas the modulus of elasticity was reduced by 9%. The fibers also presented higher dimensional stability with the hornification process. The fiber-matrix bonding was improved and the pull-out resistance of the fibers submitted to ten cycles of wetting and drying was increased by about 40% to 50%. The higher fiber-matrix bond strength contributed to an increase in the ductility and post-cracking behaviour of the composite. The fracture process was characterized by the formation of multiple cracks with the hornified sisal fibers presenting a higher ability to bridge and arrest the cracks.
The dimensional instability of vegetable fibers due to hygroscopicity results in a gradual loss of adherence in cement based composites which, when in service, are submitted to a natural variation of humidity. Such an effect reduces the contribution of the fiber as a reinforcement and can cause the early rupture of the material. In this work, a treatment of the sisal fibers is performed with the applying of wetting-drying cycles in order to alter their crystalline structure and improve the dimensional stability of the fiber to withstand the variation of humidity: 6, 10, 20, 30 and 34 cycles were applied in order to evaluate the effect on the properties of fiber; a tensile test, the morphological characterization (MEV) and the evaluation of the chemical structure of fiber were carried out. The effect of the treatment on fiber-matrix behavior was evaluated using the pull-out test. Embedded lengths of 16, 20, 30, 40 and 44 mm were defined through a factorial design and used in the test. It is verified that the use of 10 wetting-drying cycles causes less damage to the tensile strength and the elastic modulus of the fiber and contributes to a better adherence with the matrix, with an increase of up to 23 % compared with the untreated fiber. The statistical analysis of the interaction effect between the studied factors, using 2K factorial design with central composite design, indicates that the number of cycles can be decreased when using a longer length of the embedded fiber.Keywords: wetting-drying cycles, pull out test, tensile strength..
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