A high-quality
nanoscale oxide layer with a high dielectric constant
and a low leakage current prepared at a low thermal budget is critical
to advanced metal–insulator–metal (MIM) devices. In
this study, the film density, crystallinity, dielectric constant,
and leakage current of the ZrO2 thin film are significantly
improved by the atomic layer annealing (ALA) and the titanium nitride
(TiN) capping layer effect at a low process temperature of only 300
°C without any postannealing treatment. Hence a high ZrO2 dielectric constant of 35.2, a low equivalent oxide thickness
of 0.64 nm, and a leakage current density lower than 10–7 A/cm2 are demonstrated in the MIM capacitors. This study
demonstrates the significant impacts of the ALA and capping layer
effects on the film quality and electrical characteristics of nanoscale
thin films for high-performance devices.