Researchers are paying attention to the current trend of electric vehicles (EVs), but there are not many places to charge them and serve as electric vehicle charging stations (EVCSs). In order to prevent the lack of EVCS for battery EVs (BEVs) on any road with all modes of operation, this paper proposed the design of a novel configuration and control structures for the isolated charging station (ICS) based on the solar PV system for efficient energy utilization to charge battery EVs (BEVs) with flexible double function cascaded converter (MPPT and DC-link voltage regulation). This was done with the aid of a battery energy storage system (BESS) as a backup/auxiliary source. The PV system is reliant on solar radiation and the daily load profile. Therefore, the BESS is employed to provide continuous power to BEVs and overcome PV’s intermittent nature. The cascaded converter is used to achieve the MPP and to regulate the DC-link voltage to its reference value (100 V), while the buck-boost matching bidirectional DC-DC voltage converters (MBDVCs) are used for charging and discharging mode/buck and boost mode, respectively, of BEVs and BESSs. Additionally, the MBDVCs are used as an interface between the ICS sources with the load through the developed control systems. The outcomes of various operating modes show that the system functions effectively. To verify the system performance, the MATLAB/Simulink application builds the system setup.