In this report, we present a stepped laser-ablation method for the fabrication of concave micromirrors in rectangular optical waveguides. The numerically simulated vertical coupling loss of the reflection of the concave micromirror can be reduced to 1.53 dB. The processing parameters of the utilized excimer laser, such as the step number, width, and depth, were optimized to fabricate the concave micromirrors. After the thermal reflow process, the measured curve of the circular concave micromirrors obtained using a 3D optical profiler agreed well with a standard circle with a surface roughness of 39.56 nm. Furthermore, vertical coupling for 62.5 µm MMF revealed that the loss of the circular concave micromirror coated with a 50 nm thick Au film is as low as 1.83 dB, corresponding to a high coupling efficiency of 65.61%. This new, convenient, and efficient fabrication technology for the fabrication of concave micromirrors can be applied to vertical coupling for optical printed circuit board (OPCB) interconnection technology.