Design and fabrication of novel thiourea coordination compounds as potent inhibitors of bacterial growth

Rakhshani, Sajjad; Rezvani, Ali Reza; Dušek, Michal; Eigner, Václav

doi:10.1038/s41429-019-0147-2

Cited by 7 publications

(3 citation statements)

References 52 publications

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“…OPEN ACCESS complex involves in the irreversible ring-opening step. However, determination of its structure was hampered by multiple ambiguities such as tautomeric forms and coordination mode of thiourea, [65][66][67][68][69][70] no precedent of zirconocene(III)thiourea structure, 71,72 and possibility of dinuclear complex. 47,72 In our preliminary NMR studies, multiple signals indicating complexation between zirconocene(IV) and thiourea were observed.…”

Section: Llmentioning

confidence: 99%

Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

Aida

Hirao

Funabashi

et al. 2022

Chem

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Section: Llmentioning

confidence: 99%

Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

Aida

Hirao

Funabashi

et al. 2022

Chem

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“…Depending on the metal and on the substituents, it can complex either with the sulfur 126 or with the sulfur and one nitrogen of the amide group (only for substituted thioureas). 127 Introducing a metal salt to a solution of thiourea and subsequent heating leads first to the formation of these complexes and then to the decomposition to metal sulfide nanomaterials (Fig. 8a).…”

Section: Sulfur Sources For Colloidal Metal Sulfide Nanocrystal Synth...mentioning

confidence: 99%

Unravelling the intricacies of solvents and sulfur sources in colloidal synthesis of metal sulfide semiconductor nanocrystals

Mauritz,

Crisp

2024

J. Mater. Chem. C

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“…The transition metal complexes of thioureas coat a widespread range of different applications due to their behavior enhancement through the nature of sulfur atom and edistribution in the metal center [28]. In recent years, a considerable literature has grown up around the metal complexes of thioureas containing nitrogen, oxygen and sulfur atoms in biological activity field [29][30][31].…”

Section: Thioureas Applications In Coordination Chemistry and Biologi...mentioning

confidence: 99%

First Row Transition Metal Complexes Derived from N, Nʹ-Substituted Thiourea: Synthesis, Geometrical Structures and Cyclic Voltammetry Probe: A Review

Al-Riyahee

Shenta

2021

basjs

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Thioureas or thiourea derivatives as organosulfur compounds are one of the most widely used ligands in different applications as we are going to discuss it extensively such as in coordination chemistry by involving them to rich sources of N, O and S atoms coordinating through S atom, S and O atoms in benzoyl derivatives or S, O and N atoms in pyridyl hetrocylic benzoyl derivatives. These hard and soft donor sites facilitate the bonding between thiourea free ligand and metal ion through one or more to make ligands behave as mono, bi or multidentate ligands to form huge and stable series of the metal complexes. The tautomerism (thiol↔thione) inside the thiourea derivatives is responsible on their flexibility which make them easy capable to coordinate in different modes. Thiourea derivatives and their metal complexes are known in biological area by possess them antibacterial, antifungal, antimalarial, antitubercular, antithyroid and insecticidal activity features. Thioureas used as vital reagent to separate metal ions, catalyst to synthesize organic compounds or as starting material to form different hetrocyclic compounds. The wide range applications of thioureas and their metal complexes has motivated specialized researchers to search new applications for these compounds and to create a novel derivatives. The goal of this article is to present historical survey of thioureas and their metal complexes focusing on: firstly, the development of their synthetic routes by explore reactants, products, catalysis and the conditions of reactions. Secondly: investigation of the geometrical shapes of the produced complexes are reviewed as well as to the coordinated sites with metal centers. Lastly, the electrochemical manners have been lighted by employing cyclic voltammetry (CV) to study the electrochemical behavior of free ligands and their complexes to confirm the oxidation state of the metal ion in its complexes.

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Design and fabrication of novel thiourea coordination compounds as potent inhibitors of bacterial growth

Cited by 7 publications

References 52 publications

Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

Catalytic reductive ring opening of epoxides enabled by zirconocene and photoredox catalysis

Unravelling the intricacies of solvents and sulfur sources in colloidal synthesis of metal sulfide semiconductor nanocrystals

First Row Transition Metal Complexes Derived from N, Nʹ-Substituted Thiourea: Synthesis, Geometrical Structures and Cyclic Voltammetry Probe: A Review

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