This paper presents a novel configuration of Hybrid Electric Vehicle (HEV) with fuel cell as primary source and an on-board Photovoltaic (PV) array as secondary source. It incorporates an advanced Model Predictive Control (MPC) system that utilizes Artificial Neural Network (ANN) technology to control induction motor of electric vehicle. The system has three main parts: a fuel cell, an electrolyzer, and a PV array. Each part has a different job in supplying power to the vehicle. The PV array functions to supplement the fuel cell by providing power when ample irradiation is available. When the car isn't being used, the extra power from the solar panels goes to the electrolyzer. There, it turns into chemical energy, making hydrogen. This hydrogen is stored in the onboard hydrogen tank for future use. To fulfil the voltage needs of both the motor and energy sources, a quadratic bidirectional buck-boost converter (QBBC) is utilized. This converter efficiently manages the voltage output while ensuring compatibility with various energy sources. The system undergoes comprehensive analysis under different irradiance and speed conditions to evaluate its performance and efficiency. To make the solar power system more efficient and cost-effective, a Maximum Power Point Tracking (MPPT) algorithm is used. This algorithm helps get the maximum power from the PV system. An improved incremental conductance algorithm is used for this, making sure it accurately finds the best power point. The control strategy incorporates both outer voltage and inner current control, to effectively control the DC output voltage of the QBBC. The vehicle's drive system employs an indirect vector-controlled induction motor. To regulate the motor's speed effectively, an advanced ANN-MPC system is used, providing precise control and high efficiency. This paper introduces a novel approach for predictive torque control of AC machines, eliminating the need for weighting factors. An ANN estimator is used to accurately expect the motor speed, which improves the overall performance of the control system. By using MATLAB/SIMULINK to test how well the proposed Electric Vehicle (EV) setup works and make sure it's effective in real-life situations. Through this comprehensive approach, the paper contributes to advancing the development of efficient and intelligent electric vehicle systems..