2022
DOI: 10.1016/j.fuproc.2021.107056
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Design and preparation of liquid polycyclic norbornanes as potential high performance fuels for aerospace propulsion

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Cited by 18 publications
(10 citation statements)
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“…The synthesis of hydrocarbons bearing two norbornane cycles at a spiro-carbon atom was a challenge. Recently, we have shown that such polycyclic compounds could demonstrate increased density and high values of volumetric heat of combustion . However, the first attempt to synthesize hydrocarbon 9 via the [4π + 2π] reaction between 6 and 2 failed due to a poor reactivity of the CC bond of 6 in the [4π + 2π] reaction and steric hindrances (Figure ).…”
Section: Resultsmentioning
confidence: 99%
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“…The synthesis of hydrocarbons bearing two norbornane cycles at a spiro-carbon atom was a challenge. Recently, we have shown that such polycyclic compounds could demonstrate increased density and high values of volumetric heat of combustion . However, the first attempt to synthesize hydrocarbon 9 via the [4π + 2π] reaction between 6 and 2 failed due to a poor reactivity of the CC bond of 6 in the [4π + 2π] reaction and steric hindrances (Figure ).…”
Section: Resultsmentioning
confidence: 99%
“…Recently, we have shown that such polycyclic compounds could demonstrate increased density and high values of volumetric heat of combustion. 32 However, the first attempt to synthesize hydrocarbon 9 via the [4π + 2π] reaction between 6 and 2 failed due to a poor reactivity of the C�C bond of 6 in the [4π + 2π] reaction and steric hindrances (Figure 3). We decided to activate the double bond in 6 by introducing a carbonyl group to the adjacent carbon atom (10, Figure 4 and Table S1).…”
Section: Strained Hydrocarbons Frommentioning
confidence: 99%
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“…Increasing the number of strained cycles in a molecule results in higher specific energy in the case of polycyclic compounds, especially three‐cyclic compounds. The stress‐energy of small cycles has a beneficial effect on the heat of combustion [8].…”
Section: Introductionmentioning
confidence: 99%