Abstract. High-reflectance mirrors, fabricated by use of fluoride coating materials, were irradiated for extended periods by a 193-nm kilohertz repetitive laser source. This irradiation promoted a spectral shift in the reflectance band towards shorter wavelengths. In efforts to determine the mechanism for the observed spectral shifts, various models were investigated by employing such techniques as spectrophotometry, surface profile interferometry, coating design simulation, and x-ray diffraction. The result of the investigation indicates that layers near the top surface of the coating structure underwent densification, which resulted in the observed spectral shift.