Design for a Pure-Blue-Emissive Polymer Film through the Selective Perturbation of the Energy Level of the Highest Occupied Molecular Orbital in a Boron Complex
Abstract:The
logical design for obtaining a blue-luminescent film based
on a conjugated polymer is demonstrated. We recently found solid-state
luminescent boron complexes with fused ketoiminate ligands (FBKIs).
From quantum chemical calculations, it was proposed that there is
a skeletal carbon having isolated highest occupied molecular orbital
(HOMO) where the lobe in HOMO and the node in lowest unoccupied molecular
orbital (LUMO) exist. From these results, we presumed that only the
HOMO energy level could be selective… Show more
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