The overall appearance perception is affected by luminance perception accuracy and efficiency mostly. The surface luminance prediction correlated with surface angle and surface tone value was performed by measuring and modeling the paper model surface luminance. First, we used a rotating bracket designed to facilitate to set the paper surface angle. Then, we set the surface angle from 5° to 85° at the interval of 5° using the designed rotating bracket. Additionally, the four primary color scales, cyan, magenta, yellow, and black, were printed and set at the designed angle. The angle-ware and tone-ware luminance was measured using spectroradiometer, CS-2000. Finally, we proposed and evaluated a mathematical model to reveal the relationship between luminance and surface angle and surface tone using the least squares method. The results indicated that the surface luminance of paper model could be predicted and obtained quickly and accurately for any surface angles and surface tone values by the proposed prediction model.