Design of Biologically Active Macromolecular Ligands and Their Luminescent Complexes with Terbium Ions

Nekrasova, Tatiana N.; Fischer, Andrei I.; Nesterova, Natalia A.; Dobrodumov, Anatoliy V.; Garshinina, Anzhelika V.; Shuvaeva, Olga D.; Zakharova, Natalya V.; Panarin, Evgenii F.

doi:10.1007/s10118-024-3081-0

Chin J Polym Sci

2024

DOI: 10.1007/s10118-024-3081-0

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Design of Biologically Active Macromolecular Ligands and Their Luminescent Complexes with Terbium Ions

Tatiana N. Nekrasova,

Andrei I. Fischer,

Natalia A. Nesterova

et al.

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2024

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Cited by 1 publication

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Copolymers of Vinylphosphonic and p‐Methacrylamidobenzoic Acids and their Complexes with Lanthanide Ions

Nekrasova,

Nazarova,

Fischer

et al. 2024

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New copolymers of vinylphosphonic and p‐methacrylamidobenzoic acids of varying compositions were synthesized via free radical copolymerization. The structure of the obtained polymers was confirmed by NMR and FTIR spectroscopy. As the proportion of vinylphosphonic acid in the initial reaction mixture increased, the yield of the copolymer and its molecular mass both decreased. The synthesized copolymers were found to form stable soluble luminescent complexes in dilute aqueous solutions, with a concentration range of 0.002 to 0.02 mg/ml. An increase in the concentration of vinylphosphonic acid moieties in copolymers was accompanied by a noticeable decrease in the luminescence intensity. The new copolymers’ ability to bind efficiently with lanthanide ions renders them a promising material for the design of polymeric contrast agents, preparations for radioimmunotherapy and photodynamic therapy.

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Copolymers of Vinylphosphonic and p‐Methacrylamidobenzoic Acids and their Complexes with Lanthanide Ions

Nekrasova,

Nazarova,

Fischer

et al. 2024

ChemistrySelect

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Design of Biologically Active Macromolecular Ligands and Their Luminescent Complexes with Terbium Ions

Cited by 1 publication

References 23 publications

Copolymers of Vinylphosphonic and p‐Methacrylamidobenzoic Acids and their Complexes with Lanthanide Ions

Copolymers of Vinylphosphonic and p‐Methacrylamidobenzoic Acids and their Complexes with Lanthanide Ions

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