Microwave absorption in the low-frequency region is a
major challenge
in the development of carbon-based absorbers. Fe3O4–graphite composites with both low-frequency region
and high-frequency region absorption were prepared through a facile
solvothermal method. The electromagnetic properties and impedance
matching characteristics of the samples were regulated by changing
the dosage of graphite. Interestingly, an excellent bimodal microwave
absorption (MA) performance was obtained when the molar ratio of iron
and graphite was 3:10 (Fe3O4–2PG). With
the optimal matching thickness of 4 mm, the Fe3O4–2PG sample shows good performances with respect to the effective
absorption bandwidth of 3.3 GHz; the minimum reflection loss (RLmin) in C-band (4–8 GHz) is −40.6 dB, and its
RLmin in Ku-band (12–18 GHz) is −29.82 dB.
The good bimodal MA performance of Fe3O4–2PG
could be attributed to the synergistic effects and interfacial polarization
between Fe3O4 nanoparticles and graphite. Furthermore,
Fe3O4–2PG and Fe3O4–1PG have electromagnetic absorption peaks in both the C-band
and Ku-band, which broaden the absorption band of electromagnetic
waves, which is beneficial to solve the problem of 5 G electromagnetic
radiation. Therefore, the research results have special significance
for the radiation interference of 5 G technology and the shielding
absorption of C-band radar waves.