As one of the three payloads of the Advanced Space-based
Solar Observatory (ASO-S), the pre-launch characterization of HXI
includes the characterization of the collimator and the
spectrometer. This article focuses on the pre-launch
characterization of HXI's spectrometer, including detection
efficiency, energy resolution, and energy to ADC channel (E-C)
relationship. The detection efficiency characterization necessitates
a sufficient number of calibrated energy points in the HXI
observation energy range, with a refined measurement around the
absorption edge of the lanthanum bromide crystal, and is calibrated
with an X-ray beam. The characterization results are consistent with
the simulations and show that the detection efficiency difference
between detector modules is controlled within ±3%. Radioactive
sources 133Ba and 137Cs are used to
calibrate the energy resolution and E-C relationship. The
characterization results show that all detector modules' energy
resolutions are better than 26% at 32 keV, meeting the design
specification. And their E-C relationships vary regularly with
voltage. All of the characterization results indicate that the
flight model of the HXI spectrometer meets the performance
requirements and is capable of performing on-orbit observation
activities.