Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification

Zhao, Jiaheng; Wu, Xiuping; Zhang, Yanjie; Yu, Jingjie; Wang, Huiyuan; Li, Bing

doi:10.1016/j.jlumin.2022.119273

Cited by 10 publications

(1 citation statement)

References 53 publications

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“…A number of borophosphate materials have been prepared, for example, M 2 BP 3 O 12 (M = Fe, Cr) shows interesting magnetic properties, Ba 8 {Ni, Mn} 4 [BP 3 O 11 (OH) 2 ] 4 has a new “anti-zeolite” structure with a positively charged framework, MBPO 5 (M = Sr and Ba), Na 3 Cd 3 B(PO 4 ) 4, AMBP 2 O 8 (A = K, M = Sr, Ba; A = K, Rb, M = Pb), − and β-Zn 3 (BO 3 )(PO 4 ) are potential nonlinear optical materials. The Eu 2+ -doped Ba 3 BP 3 O 12 is a new scintillation material .…”

Section: Introductionmentioning

confidence: 99%

Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates

Hao,

Deng,

Chen

et al. 2024

Inorg. Chem.

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Two remarkable aluminum borophosphates (AlBPOs), namely, Na 3 [Al 2 B 6 P 4 O 22 (OH) 3 ](H 2 O) 6 (denoted as ABPO1) and Na 3 [Al 2 BP 2 O 11 ](H 2 O) 0.5 (denoted as ABPO2), have been designed and prepared by low-temperature flux syntheses. The exceptional open framework structure of ABPO1 is formed by a unique microanionic network [Al 2 B 6 P 4 O 22 (OH) 3 ] n 3−, which contains three types of 8-, 12-, and 16-membered ring (MR) tunnels. Interestingly, these tunnels are featured by a type of supernanocage as large as ∼1.753 nm × 1.753 nm × 1.753 nm, which is the first example of AlBPOs containing extra-large cages. Importantly, it was found that Na + can be partially exchanged by K + , Sr 2+ , Cd 2+ , and Ni 2+ , which means that it is a potential ionic exchanger for removing radionuclides and toxic cations. The structure of ABPO2 features a unique 2D anionic AlBPO layer composed of corner-sharing AlO 6 octahedra and AlO 4 , BO 4 , and PO 4 tetrahedra. To the best of our knowledge, this is the first example of both AlO 6 octahedra and AlO 4 tetrahedra being contained in the structure. 9-MRs can be observed along the b-axis. Herein, the syntheses and topological structures of ABPO1 and ABPO2 as well as elemental analysis, thermal stability, infrared spectroscopy, UV−vis diffuse reflectance, structural properties, and ionic exchange properties are also discussed.

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Section: Introductionmentioning

confidence: 99%

Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates

Hao,

Deng,

Chen

et al. 2024

Inorg. Chem.

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Spectral tunability of K2Lu(WO4)(PO4): Dy3+, Eu3+ phosphors and remote luminescent layers for high-quality white light

Zhao,

Zhang,

Yang

et al. 2024

Ceramics International

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Effect of oxygen vacancy on photoluminescence properties of Dy3+ doped K2BaCa(PO4)2 phosphor and remote luminescence multi-layer for white light

Zhao

Wang

Zhao

et al. 2023

Journal of Alloys and Compounds

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Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification

Cited by 10 publications

References 53 publications

Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates

Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates

Spectral tunability of K2Lu(WO4)(PO4): Dy3+, Eu3+ phosphors and remote luminescent layers for high-quality white light

Effect of oxygen vacancy on photoluminescence properties of Dy3+ doped K2BaCa(PO4)2 phosphor and remote luminescence multi-layer for white light

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Design of K2SrCa(PO4)2-x(BO3)x:Eu2+ phosphors with full-visible spectrum by crystal structure modification

Cited by 10 publications

References 53 publications

Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

Na3[Al2B6P4O22(OH)3](H2O)6 and Na3[Al2BP2O11](H2O)0.5: Two Remarkable Complex Aluminum Borophosphates

Spectral tunability of K2Lu(WO4)(PO4): Dy3+, Eu3+ phosphors and remote luminescent layers for high-quality white light

Effect of oxygen vacancy on photoluminescence properties of Dy3+ doped K2BaCa(PO4)2 phosphor and remote luminescence multi-layer for white light

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Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates

Na₃[Al₂B₆P₄O₂₂(OH)₃](H₂O)₆ and Na₃[Al₂BP₂O₁₁](H₂O)_0.5: Two Remarkable Complex Aluminum Borophosphates