Design principle and synthetic strategy for metal-organic framework composites

Shen, Zizhou; Peng, Yi; Li, Xia; Li, Nana; Xu, Hengyue; Li, Wenting; Guo, Xiaotian; Pang, Huan

doi:10.1016/j.coco.2024.101933

Composites Communications

2024

DOI: 10.1016/j.coco.2024.101933

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Design principle and synthetic strategy for metal-organic framework composites

Zizhou Shen,

Yi Peng,

Xia Li

et al.

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Cited by 2 publications

References 297 publications

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ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

Shao,

Han,

Zhu

et al. 2025

Separation and Purification Technology

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ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

Shao,

Han,

Zhu

et al. 2025

Separation and Purification Technology

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p–d Orbital Hybridization in Pd₃Sn Metallic Aerogels Boosts Alcohol Electrooxidation

Guan,

Fu,

Zhu

et al. 2024

Chem. Mater.

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Orbital engineering of nanomaterials has been proven to be a compelling strategy, which stimulates the synthesis of palladium (Pd)-based nanomaterials with p−d orbital hybridization and the exploration of their electrocatalytic properties. Herein, Pd 3 Sn metallic aerogels (Pd 3 Sn MAs) with p−d orbital hybridization were reasonably constructed as efficient electrocatalysts for alcohol electrooxidation. In particular, the mass activity and specific activity of Pd 3 Sn MAs for the ethylene glycol oxidation reaction are 1.69 A mg Pd −1 and 3.56 mA cm Pd −2, respectively, superior to Pd MAs and commercial Pd/C. Meanwhile, benefiting from the excellent antipoisoning properties, Pd 3 Sn MAs still maintain satisfactory activity after long-term durability tests. Moreover, the same trend can be observed in reactions such as the methanol oxidation reaction, the ethanol oxidation reaction, and the glycerol oxidation reaction. Furthermore, density functional theory calculations reveal that the p−d orbital hybridization of Pd 3 Sn MAs precisely regulates the electronic structure and d-band center of Pd and also decreases the reaction energy barrier in the rate-determining step, thus reactivating the surface of Pd 3 Sn MAs. This study provides a broad prospect for the design of efficient fuel cell electrocatalysts through orbital engineering.

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Design principle and synthetic strategy for metal-organic framework composites

Cited by 2 publications

References 297 publications

ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

p–d Orbital Hybridization in Pd₃Sn Metallic Aerogels Boosts Alcohol Electrooxidation

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Design principle and synthetic strategy for metal-organic framework composites

Cited by 2 publications

References 297 publications

ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

ZIF-8-modified multiscale polyurethane/flexible polyurethane nanofiber membrane for multifunctional adsorption of formaldehyde, antibacterial and anti-haze window screen

p–d Orbital Hybridization in Pd3Sn Metallic Aerogels Boosts Alcohol Electrooxidation

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Product

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p–d Orbital Hybridization in Pd₃Sn Metallic Aerogels Boosts Alcohol Electrooxidation