Design strategies for dielectric metal–organic frameworks and their applications in microelectronic devices

Inamdar, Arif I.; Kamal, Saqib; Usman, Muhammad; Chiang, Ming-Hsi; Lu, Kuang-Lieh

doi:10.1016/j.ccr.2023.215596

Cited by 8 publications

(1 citation statement)

References 192 publications

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“…This research field has rapidly developed in the past two decades. 17 MOFs can immobilize active functional materials and manufacture highly controllable nanostructures as carriers, providing new materials for energy applications. 18 A new photocatalyst, MgAl LDH/Zn-MOF, successfully designed and synthesized, is reported in this work.…”

Section: Introductionmentioning

confidence: 99%

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption

Maseeh,

Anwar,

Aroob

et al. 2024

Mater. Adv.

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Section: Introductionmentioning

confidence: 99%

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption

Maseeh,

Anwar,

Aroob

et al. 2024

Mater. Adv.

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Enhancing Oxygen Evolution Reaction Performance of Metal‐Organic Frameworks through Cathode Activation

Dong,

Boukhvalov,

et al. 2024

ChemSusChem

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Due to their abundant active sites and porous structures, metal‐organic frameworks (MOFs) have garnered significant interest as oxygen evolution reaction (OER) electrocatalysts. Nevertheless, the development of MOF‐based electrocatalysts with efficient OER activity and excellent stability simultaneously still faces challenges. Herein, a cathodic activation strategy was used to enhance the OER electrocatalytic performance of M‐HHTP for the first time, where M refers to Ni, Cu, Co, Fe, while HHTP denotes 2, 3, 6, 7, 10, 11‐hexahydroxytriphenylene. As a prototype, the activated Ni‐HHTP (HA‐Ni‐HHTP) demonstrates outstanding OER performance, with an overpotential as low as 140 mV at 20 mA cm‐2 and a small Tafel slope of 78.7 mV‐1, surpassing commercial RuO2 and rivaling state‐of‐the‐art MOFs‐based electrocatalysts. Characterizations and density functional theory calculations reveal that the superior performance of HA‐Ni‐HHTP is primarily ascribed to changes in semiconductor type, contact angle, and oxygen vacancy content induced by cathodic activation. Electrochemical impedance spectroscopy analysis using the transmission line model confirms that cathodic activation accelerates charge transport, enhancing the OER process. Furthermore, the cathodic activation strategy holds promise for improving the water oxidation performance of other MOFs such as Fe‐HHTP, Co‐HHTP, and Cu‐HHTP.

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Vanadium- and manganese-based metal-organic frameworks for potential environmental and catalysis applications

Pan,

Sanati,

Abazari

et al. 2025

Coordination Chemistry Reviews

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Design strategies for dielectric metal–organic frameworks and their applications in microelectronic devices

Cited by 8 publications

References 192 publications

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption

Enhancing Oxygen Evolution Reaction Performance of Metal‐Organic Frameworks through Cathode Activation

Vanadium- and manganese-based metal-organic frameworks for potential environmental and catalysis applications

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Design strategies for dielectric metal–organic frameworks and their applications in microelectronic devices

Cited by 8 publications

References 192 publications

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO2 adsorption

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO2 adsorption

Enhancing Oxygen Evolution Reaction Performance of Metal‐Organic Frameworks through Cathode Activation

Vanadium- and manganese-based metal-organic frameworks for potential environmental and catalysis applications

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Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption

Multifunctional MgAl LDH/Zn-MOF S-scheme heterojunction: efficient hydrogen production, methyl red removal, and CO₂ adsorption