2018
DOI: 10.1002/macp.201700392
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Design, Synthesis, and Photophysical Property of Strongly Fluorescent Benzofuran–Ethynylene Copolymer

Abstract: A novel alternating benzofuran–ethynylene copolymer is designed and synthesized through a series of palladium‐catalyzed reactions, and extremely strong fluorescence is observed. The electronic levels of frontier orbitals are estimated by electrochemical and photophysical measurements for copolymer and corresponding monomers. The extension of π‐electron conjugation is shown after polymerization reaction, in which the energy of highest occupied molecular orbital (HOMO) is increased and that of the lowest unoccup… Show more

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