Designed fabrication of biomimetic metal–organic frameworks for catalytic applications

Chen, Kai; Wu, Chuan‐De

doi:10.1016/j.ccr.2018.01.016

Cited by 148 publications

(75 citation statements)

References 149 publications

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“…MOFs which are assembled by metal ions/clusters and organic ligands possess diversified composition, tailorable structure, large surface area, and uniform cavity. Such unique structural and compositional features make MOF‐based materials promising for a wide range of applications, such as gas storage and separation, catalysis, sensors, and drug delivery . Great efforts have been also devoted to preparing nanoscale MOF crystals with controllable size and morphology, in order to achieve enhanced performance in certain applications .…”

Section: Introductionmentioning

confidence: 99%

Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications

et al. 2019

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Low‐dimensional metal–organic frameworks (LD MOFs) have attracted increasing attention in recent years, which successfully combine the unique properties of MOFs, e.g., large surface area, tailorable structure, and uniform cavity, with the distinctive physical and chemical properties of LD nanomaterials, e.g., high aspect ratio, abundant accessible active sites, and flexibility. Significant progress has been made in the morphological and structural regulation of LD MOFs in recent years. It is still of great significance to further explore the synthetic principles and dimensional‐dependent properties of LD MOFs. In this review, recent progress in the synthesis of LD MOF‐based materials and their applications are summarized, with an emphasis on the distinctive advantages of LD MOFs over their bulk counterparties. First, the unique physical and chemical properties of LD MOF‐based materials are briefly introduced. Synthetic strategies of various LD MOFs, including 1D MOFs, 2D MOFs, and LD MOF‐based composites, as well as their derivatives, are then summarized. Furthermore, the potential applications of LD MOF‐based materials in catalysis, energy storage, gas adsorption and separation, and sensing are introduced. Finally, challenges and opportunities of this fascinating research field are proposed.

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Section: Introductionmentioning

confidence: 99%

Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications

et al. 2019

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“…These are conceptually distinct approaches that have been extensively reviewed elsewhere. 9,[11][12][13][14][15]…”

Section: Biomimetic Chemistries In Crystalline Porous Materialsmentioning

confidence: 99%

Bioinspired chemistry at MOF secondary building units

Bour

Wright

et al. 2020

Chem. Sci.

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“… 10 Furthermore, the functional diversity of the metal nodes and organic linkers may be capitalized on to catalyze synthetic organic and biomimetic reactions and to facilitate concurrent cascade reactions. 11 , 12 The practical application of porous materials critically relies on the specific interactions with guest molecules. Thus, a comprehensive understanding of enzyme behavior within confined space is important for guiding the design of enzyme@MOF biocomposites for specific functions.…”

Section: Introductionmentioning

confidence: 99%

Metal–Organic Frameworks for Enzyme Immobilization: Beyond Host Matrix Materials

2020

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Enzyme immobilization in metal–organic frameworks (MOFs) as a promising strategy is attracting the interest of scientists from different disciplines with the expansion of MOFs’ development. Different from other traditional host materials, their unique strengths of high surface areas, large yet adjustable pore sizes, functionalizable pore walls, and diverse architectures make MOFs an ideal platform to investigate hosted enzymes, which is critical to the industrial and commercial process. In addition to the protective function of MOFs, the extensive roles of MOFs in the enzyme immobilization are being well-explored by making full use of their remarkable properties like well-defined structure, high porosity, and tunable functionality. Such development shifts the focus from the exploration of immobilization strategies toward functionalization. Meanwhile, this would undoubtedly contribute to a better understanding of enzymes in regards to the structural transformation after being hosted in a confinement environment, particularly to the orientation and conformation change as well as the interplay between enzyme and matrix MOFs. In this Outlook, we target a comprehensive review of the role diversities of the host matrix MOF based on the current enzyme immobilization research, along with proposing an outlook toward the future development of this field, including the representatives of potential techniques and methodologies being capable of studying the hosted enzymes.

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Designed fabrication of biomimetic metal–organic frameworks for catalytic applications

Cited by 148 publications

References 149 publications

Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications

Structural Engineering of Low‐Dimensional Metal–Organic Frameworks: Synthesis, Properties, and Applications

Bioinspired chemistry at MOF secondary building units

Metal–Organic Frameworks for Enzyme Immobilization: Beyond Host Matrix Materials

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