2008
DOI: 10.1039/b716847k
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Designed self-assembly of a reactive metal–organic framework with quasi α-Po topology

Abstract: A 2D layered structure composed of Cd dimers, linked by fumarate anions to form a rectangular grid network, was pillared, via metal coordination, to afford a 3D photoreactive metal-organic framework.

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Cited by 21 publications
(11 citation statements)
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“…Recently, Chen and co-workers synthesized the noninterpenetrated MOF Zn 4 O(FMA) 3 (FMA = fumarate) with high rigidity and porosity, which makes it interesting for gas storage. The FMA linker is readily available and inexpensive compared to many other organic linkers and is also among the smaller MOF linkers available; it has found extensive uses in homolinked and heterolinked MOFs. Nevertheless, the finer structural details of Zn 4 O(FMA) 3 cannot be discerned from the experimental crystallographic data.…”
Section: Introductionmentioning
confidence: 99%
“…Recently, Chen and co-workers synthesized the noninterpenetrated MOF Zn 4 O(FMA) 3 (FMA = fumarate) with high rigidity and porosity, which makes it interesting for gas storage. The FMA linker is readily available and inexpensive compared to many other organic linkers and is also among the smaller MOF linkers available; it has found extensive uses in homolinked and heterolinked MOFs. Nevertheless, the finer structural details of Zn 4 O(FMA) 3 cannot be discerned from the experimental crystallographic data.…”
Section: Introductionmentioning
confidence: 99%
“…Solid state photoreactivity of muconate has been reported before by Okada as organic salts and by Michaelides in coordination polymers. Recently, we have shown the formation of the cyclooctadiene ring via concerted [4 + 4] cycloaddition reaction of muco in its gold­(I) macrocyclic complexes . Although photoreactive CC bonds have been successively aligned parallel for exhibiting solid state photoreactivity in discrete metal complexes, coordination polymers, and various types of organic salts ,, and cocrystals, , the metal–organic salts have not been yet investigated extensively in this regard. The photoreactivity of two polymorphs of K 2 SDC (where H 2 SDC is trans -4,4′-stilbene dicarboxylic acid) was reported recently .…”
Section: Introductionmentioning
confidence: 97%
“…Cadmium (as Cd 2+ ) displays rich coordination chemistry and readily forms complexes with various N-, O-, and S-donor ligands. This versatility is due to adaptable coordination geometry around Cd 2+ and to the borderline position of Cd 2+ in terms of hard–soft acid–base (HSAB) dualism. Recent developments in the field of cadmium coordination chemistry include the creation of Cd 2+ -based coordination networks featuring noncentrosymmetric metal–organic frameworks (MOF) with nonlinear-optical (NLO) properties, MOFs with photochemical building units, luminescent complexes, selective gas-sorption behavior, etc.…”
Section: Introductionmentioning
confidence: 99%
“…Recent developments in the field of cadmium coordination chemistry include the creation of Cd 2+ -based coordination networks featuring noncentrosymmetric metal–organic frameworks (MOF) with nonlinear-optical (NLO) properties, MOFs with photochemical building units, luminescent complexes, selective gas-sorption behavior, etc. Organic ligands with N- and O-donor centers are typically used in these preparations. The S-donor (as well as Se- and Te-donor) ligands are excellent auxiliary groups for stabilizing Cd x Q y “nanoclusters” (Q = S, Se, Te) with 10–32 Cd atoms, which show interesting photophysical properties. Cadmium complexes with phosphines have received less attention, even though large clusters such as [Cd 32 Se 14 (SePh) 36 (PPh 3 ) 4 ] are stabilized by phosphine coordination. Extensive studies on the coordination of CdX 2 (X = Cl, Br, I, NCS, OR, SR, NO 3 , RCOO, RCS 2 ) with PR 3 (R = Ph, tolyl, Cy, Et, Bu, SiMe 3 ) and phospholes were carried out.…”
Section: Introductionmentioning
confidence: 99%