Although the present university-level chemistry experimental curriculum has been extensive and well-designed, it lacks a connection with the scientific research field, especially the frontier field. It is crucial to incorporate recent discoveries through new experiment designs to bridge this gap and boost the value of the undergraduate experimental course. Under the background of advancing with the times, this paper integrates the scientific research results of electrocatalytic ammonia synthesis (through nitrogen reduction reaction, NRR) into the undergraduate teaching classes, which is conducive to improving students' scientific analysis ability and their green environmental awareness. Two lead dioxide catalysts with different crystal phases were prepared on a carbon cloth substrate by a simple water bath method. The structure, composition, and morphology of the two catalysts were characterized, and the electrocatalytic ammonia synthesis performance of the two catalysts was explored. This experimental project not only covers the teaching content of inorganic, analytical, and physical chemistry but also cultivates students' basic experimental operation skills and the ability to use modern instruments to analyze the structure of materials, stimulate students' interest in learning, and improve students' scientific research literacy.