Designing All‐Inorganic EuO‐Sensitized TiO₂ Solar Cell from 4f‐3d Composite Bandgap Structure

Abstract

TiO 2 dye-sensitized solar cells (DSSCs) have blazed a new trail out of traditional silicon-based photovoltaics. However, extensive applications of DSSCs are limited by the use of organic photosensitizers and liquid electrolytes, which raises strict requirements on dye synthesis and cell encapsulation. Considering the electron-donating tendency and optical activity of Eu 2+ , EuO semiconductor is chosen as inorganic substitution of organic dyes based on Eu 2+ ↔Eu 3+ redox transition. Through first-principle calculations, 4f-3d composite bandgap is found in TiO 2 /EuO heterostructure, reducing the bandgap of pure TiO 2 from 3.2 to 0.99 eV. This energy corresponds to near-infrared photon and thus covers the whole range of visible light, which will significantly enhance the light-absorption efficiency of TiO 2 . Similar electronic feature also appears in ATiO 3 (A = Sr, Ba)/EuO interfaces. The bandgap value is critically dependent on bonding type and geometry structure of TiO 6 octahedra at the interface. On this basis, all-inorganic EuO-sensitized TiO 2 solar cell is theoretically designed, where EuO serves as photosensitizer to replace dye molecules and inject electrons into TiO 2 anode under light excitation. This finding not only provides prospect for all-inorganic DSSCs, but also sheds light on high-efficiency TiO 2 -based photocatalysis and EuO-relevant spintronics with rich interfacial physics.

A Series of Singlet‐Triplet InVerted TADF Fluorescent Probes with High Stability, Low Molecular Weight, and Synthesis Accessibility

“…When only delayed fluorescence was detected by using TRLI technology, a good signal‐to‐noise ratio can be obtained in biological imaging. The typically delayed fluorescent compounds include phosphorescent transition metal (e.g., Ru(II), [ 5b,6 ] Ir(III), [ 7 ] and Pt(II) [ 8 ] ) complexes. Although the application of heavy metals can meet the requirements of the TRLI technology in biological imaging, the difficulty of their synthesis and potential physical toxicity also limit its further development.…”