This review paper provides a comprehensive analysis of the automation of smart education in the context of Industry 5.0 from 78 papers, focusing on the integration of advanced technologies and the development of innovative, effective, and ethical educational solutions for the future workforce. As the world transitions into an era characterized by human–machine collaboration and rapidly evolving technologies, there is an urgent need to recognize the pivotal role of smart education in preparing individuals for the opportunities and challenges presented by the new industrial landscape. The paper examines key components of smart education, including intelligent tutoring systems, adaptive learning environments, learning analytics, and the application of the Internet of Things (IoT) in education. It also discusses the role of advanced technologies such as artificial intelligence (AI), machine learning (ML), robotics, and augmented and virtual reality (AR/VR) in shaping personalized and immersive learning experiences. The review highlights the importance of smart education in addressing the growing demand for upskilling and reskilling, fostering a culture of lifelong learning, and promoting adaptability, resilience, and self-improvement among learners. Furthermore, the paper delves into the challenges and ethical considerations associated with the implementation of smart education, addressing issues such as data privacy, the digital divide, teacher and student readiness, and the potential biases in AI-driven systems. Through a presentation of case studies and examples of successful smart education initiatives, the review aims to inspire educators, policymakers, and industry stakeholders to collaborate and innovate in the design and implementation of effective smart education solutions. Conclusively, the paper outlines emerging trends, future directions, and potential research opportunities in the field of smart education, emphasizing the importance of continuous improvement and the integration of new technologies to ensure that education remains relevant and effective in the context of Industry 5.0. By providing a holistic understanding of the key components, challenges, and potential solutions associated with smart education, this review paper seeks to contribute to the ongoing discourse surrounding the automation of smart education and its role in preparing the workforce for the future of work.