Designing functionally graded materials with superior load-bearing properties

Abstract

Ceramic prostheses often fail from fracture and wear. We hypothesize that these failures may be substantially mitigated by an appropriate grading of elastic modulus at the ceramic surface. In this study, we elucidate the effect of elastic modulus profile on the flexural damage resistance of functionally graded materials (FGMs), providing theoretical guidlines for designing FGM with superior load-bearing property. The Young's modulus of the graded structure is assumed to vary in a power-law relation with a scaling exponent n; this is in accordance with experimental observations from our laboratory and elsewhere. Based on the theory for bending of graded beams, we examine the effect of n value and bulk-to-surface modulus ratio (Eb/Es) on stress distribution through the graded layer. Theory predicts that a low exponent (0.15 < n < 0.5), coupled with a relatively small modulus ratio (3 < Eb/Es < 6), is most desirable for reducing the maximum stress and transferring it into the interior, while keeping the surface stress low. Experimentally, we demonstrate that elastically graded materials with various n values and Eb/Es ratios can be fabricated by infiltrating alumina and zirconia with a low-modulus glass. Flexural tests show that graded alumina and zirconia with suitable values of these parameters exhibit superior load-bearing capacity, 20% to 50% higher than their homogeneous counterparts. Improving load-bearing capacity of ceramic materials could have broad impacts on biomedical, civil, structural, and an array of other engineering applications.

Sliding contact fracture of dental ceramics: Principles and validation

“…These materials were developed to improve the functionalities (e.g. aesthetic and cementation properties) [48,49] and damage resistance of homogeneous aluminas and zirconias [50–53]. Detailed fabrication process for graded alumina and zirconia can be found in Refs.…”

“… a Flexural strength. b Material data sheet from its respective manufacturer. c Measured in authors’ laboratory [33,48,49,53]. …”

On the interfacial fracture of porcelain/zirconia and graded zirconia dental structures

“…Using a glass-ceramic infiltration technique, a functionally graded glass-zirconia material has been developed [25]. Previously, we have examined the fracture resistance of this material, including subsurface flexural fracture [26–28] and edge chipping resistance [29, 30]. The results showed that this material retains the proven strength benefit of Y-TZP, yet it has a superior esthetic quality [24].…”

Dental Ceramics for Restoration and Metal Veneering

“…In modern-day zirconias, this is being achieved by fabricating more translucent microstructures, or by infiltrating glass into outer surfaces to produce graded structures. 129-135 …”