“…The prodigious advancements in conjugated polymer (CP) structural engineering over the last few decades have been directly coupled with the development of new synthetic methodologies for monomer functionalization, polymerization, and an improved understanding of the structure–function relationships that enable state-of-the-art performance metrics in electrochromic devices (ECDs), 1–4 organic photovoltaics (OPV), 5–8 organic photodiodes and phototransistors (OPD and OPTs), 9–12 organic field effect transistors (OFET), 13–16 and organic electrochemical transistors (OECTs). 17–20 Recently, significant research effort has been focused on the development of CPs with near-infrared (NIR) optical absorption (750–2500 nm) to increase light harvesting capabilities in OPV, 21,22 provide optical transparency for smart-windows and photovoltaic green houses, 23,24 enable new capabilities in active camouflage, 25,26 provide discrete, transparent electronics, 27,28 and narrow bandgaps to enable ambipolar charge transport. 14,29,30 Compared to their inorganic counterparts possessing NIR-IR optical absorption, e.g.…”