2007
DOI: 10.1016/j.jhazmat.2006.12.040
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Destruction of chemical agent simulants in a supercritical water oxidation bench-scale reactor

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Cited by 55 publications
(23 citation statements)
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“…However, TOC mean destruction efficiencies are higher when working at 400°C and 30 min reaction time. Usually, SCWO experimental studies report a positive effect of temperature when working in a continuous unit set up and with residence times of a few seconds [15], [30]. The heating time of the substance to oxidize and the oxidant agent pumped separately, is not accounted for as part of the total reaction time and could be even longer than the residence time in the reactor.…”
Section: Total Organic Carbon Anovamentioning
confidence: 99%
“…However, TOC mean destruction efficiencies are higher when working at 400°C and 30 min reaction time. Usually, SCWO experimental studies report a positive effect of temperature when working in a continuous unit set up and with residence times of a few seconds [15], [30]. The heating time of the substance to oxidize and the oxidant agent pumped separately, is not accounted for as part of the total reaction time and could be even longer than the residence time in the reactor.…”
Section: Total Organic Carbon Anovamentioning
confidence: 99%
“…The titanium tube shielded the pressure vessel from corrosion. previous paper [19,20]. Therefore, only a very short description is given below.…”
Section: The Experimental Apparatus Designmentioning
confidence: 99%
“…In these AOPs treatment methods, the generation of sufficient reactive species such as hydroxyl radicals (•OH) leads to the effective decomposition of organic pollutants [6,7] . Wet oxidation has shown its effectiveness and promising property with several industrial effluents, including benzene, biphenyls, amines and pyridine [8][9][10][11] .This process performed the liquid-phase oxidation of toxic or poorly biodegradable compounds under high temperature (150~350 °C) and pressure (2.0~15.0 MPa) conditions, using a gaseous source of oxygen or air. During this process, the pollutants were oxidized completely [12,13] .…”
Section: Introductionmentioning
confidence: 99%