“…29 The chirality of the peripheral groups controls the helicity, M or P , of the primary fibres, and, moreover, non‐linear effects, that is, “sergeants‐and‐soldiers”30 and “majority rules”,31 have been evidenced by CD studies. Desymmetrisation of the C 3 platform allowed the modulation of the number of chiral units, the nature of the appended groups, and, ultimately, the self‐assembly properties 32. 33 To prepare electroactive supramolecular aggregates, we have recently attached thioalkyl containing TTF units to the 3,3′‐bis(acylamino)‐2,2′‐bipyridine‐substituted benzene‐1,3,5‐tricarboxamide (BiPy‐BTA) moieties.…”