Detailed analysis of sulfur compounds in gasoline range petroleum products with high-resolution gas chromatography–atomic emission detection using group-selective chemical treatment

Stumpf, Árpád; Tolvaj, Krisztina; Juhász, Miklós

doi:10.1016/s0021-9673(98)00444-0

Cited by 64 publications

(39 citation statements)

References 7 publications

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“…Organic sulfur compounds in crude oils are distributed over a wide range of molecular structures: aliphatic thiols, mono-and disulfides are sometimes present (Rygle et al, 1984) as well as alkyl phenyl disulfides (Nishioka, 1988), but a large amount occurs in aromatic structures, especially as alkylated thiophene benzologues (Arpino et al, 1987). After distillation, mercaptanes, sulfides, and thiophenes are concentrated in the gasoline-range products (Stumpf et al, 1998) while benzothiophenes (BTs), dibenzothiophene (DBT), and alkylated dibenzothiophenes (DBTs) are concentrated in the middle distillate fractions. They may represent up to 70% of the sulfur present in diesel fuel.…”

Section: Sulfur Compounds In Crude Oil and Petroleum Productsmentioning

confidence: 99%

“…Under normal conditions for HDS, the most reactive and easiest-to-remove classes of sulfur compounds are thiols, sulfides, and disulfides; compounds such as substituted BTs and DBTs react somewhat more sluggishly (Mössner and Wise, 1999;Lamure-Meille et al, 1995;Shafi and Hutchings, 2000;Knudsen et al, 1999;Stumpf et al, 1998).…”

Section: Influence Of Refinery Processes On Pash Patternsmentioning

confidence: 99%

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Characterization of polycyclic aromatic sulfur heterocycles for source identification

Hegazi

Andersson

2007

Oil Spill Environmental Forensics

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Section: Sulfur Compounds In Crude Oil and Petroleum Productsmentioning

confidence: 99%

Section: Influence Of Refinery Processes On Pash Patternsmentioning

confidence: 99%

Characterization of polycyclic aromatic sulfur heterocycles for source identification

Hegazi

Andersson

2007

Oil Spill Environmental Forensics

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“…Little has been reported on the influence of sulfur species in FCC gasoline on membrane performance for FCC gasoline desulfurization. Typical sulfur compounds in gasoline were thiophene species, mercaptans and sulfides [14][15][16]. Sulfur species will produce considerable effect on pervaporation separation performance.…”

Section: Introductionmentioning

confidence: 99%

Pervaporation separation of n-heptane/sulfur species mixtures with polydimethylsiloxane membranes

Zhao

et al. 2008

Separation and Purification Technology

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a b s t r a c tWith the mixtures of n-heptane and different sulfur species making up the model gasoline, polydimethylsiloxane (PDMS)/polyetherimide (PEI) composite membranes were prepared and used for sulfur removal from gasoline. Effects of sulfur species, feed sulfur content and feed temperature on the desulfurization efficiency were investigated for a series of binary n-heptane/sulfur species mixtures by pervaporation. Experimental results indicated that the change of feed sulfur content produced insignificant effect on sulfur enrichment factor for every sulfur species, while the partial fluxes of sulfur species were proportional to feed sulfur content. With the feed temperature increase, total flux increased for every binary mixture. Sulfur enrichment factor decreased in the following order at the same temperature: thiophene > 2-methylthiophene > 2,5-dimethylthiophene > n-butyl mercaptan > n-butyl sulfide. Correspondingly activation energy of permeation was also obtained. In order to simulate the desulfurization process of real gasoline, effect of more sulfur species coupling exist on separation efficiency was also investigated. With the increase of sulfur species number according to the decrease order of sulfur enrichment factor, total sulfur enrichment factor decreased while total flux was almost invariable.Crown

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“…Saturated hydrocarbons According to the standard samples, the types of sulfides in oil phase between 450˚C -550˚C were detected and quantified by GC-PFPD. Qualitative research on oil phase sulfides was carried out in terms of the spectrum of standard sulfide and the experiential molecular formula of sulfide, boiling point and the references [14,15]. It is shown that if a sulfide compound has fewer substituent groups or the substituent groups have a closer position, the retention time is always short.…”

Section: Analysis Of Oil Phase Productsmentioning

confidence: 99%

Simulation Experiments and Kinetics for the Formation of Organic Sulfide in Marine Carbonate Reservoirs

Yue¹,

Li²,

Zhang³

2012

OJG

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Thermal simulation experiments on the system of gasoline and magnesium sulfate were carried out using an autoclave operating at high temperature and high pressure in the presence of water. Properties of the gas-oil-solid 3-phase products were analyzed by some advanced analytical methods including gas chromatography, microcoulometry, capillary gas chromatography in combination with a pulsed flame photometric detector, FT-IR and X-ray diffraction. The results showed that the reaction could proceed at 450˚C -550˚C to produce MgO, S, C, H 2 S, CO 2 and a series of organic sulfides such as mercaptans, sulfoethers and thiophenes as the main products. According to the reaction kinetics, the calculated activation energy of the reaction is 68.9 kJ·mol −1 .

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Detailed analysis of sulfur compounds in gasoline range petroleum products with high-resolution gas chromatography–atomic emission detection using group-selective chemical treatment

Cited by 64 publications

References 7 publications

Characterization of polycyclic aromatic sulfur heterocycles for source identification

Characterization of polycyclic aromatic sulfur heterocycles for source identification

Pervaporation separation of n-heptane/sulfur species mixtures with polydimethylsiloxane membranes

Simulation Experiments and Kinetics for the Formation of Organic Sulfide in Marine Carbonate Reservoirs

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