a b s t r a c tOxidizer-and temperature-dependent soot properties were investigated to better understand soot oxidation process. For this work, partially oxidized Printex-U samples as surrogate soot, under three different O 2 -NO 2 mixtures, were analyzed by using the high resolution-transmission electron microscope, Raman microscope and Fourier transform infrared spectroscopy-attenuated total reflectance. The results show that the maturing process was much dependent on NO 2 content in the O 2 -NO 2 mixture: with no NO 2 added, soot oxidized through the internal-burning out process, whereas with increased NO 2 in the mixture, soot tended to oxidize through the external burning process. As the NO 2 content increased, the preferential oxidation of less-ordered carbon crystallites decreased and as a result the maturing process was delayed. Internal burning-out process by O 2 only was also verified at various temperatures and with actual engine soot such as diesel soot and gasoline direct-injection (GDI) soot by TEM observations. Despite similar internal burning-out process, however, it was shown that oxidation at increased temperature resulted in relatively less-ordered soot, implying that soot maturing process was delayed with temperature. Since soot oxidation rate increased with temperature, the increase in oxidation temperature seems to diminish preference on short-ranged crystallites like more efficient O 2 -NO 2 cases.