Detailed mechanism and kinetics of reactions of anti- and syn-CH3CHOO with HC(O)OH: infrared spectra of conformers of hydroperoxyethyl formate

Behera, Bedabyas; Lee, Yuan-Pern

doi:10.1039/d3cp04086k

Phys. Chem. Chem. Phys.

2024

DOI: 10.1039/d3cp04086k

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Detailed mechanism and kinetics of reactions of anti- and syn-CH₃CHOO with HC(O)OH: infrared spectra of conformers of hydroperoxyethyl formate

Bedabyas Behera,

Yuan-Pern Lee

Abstract: We observed IR absorption of three conformers of HPEF from CH3CHOO + HC(O)OH. The open-form conformers P2/P3 rapidly convert to P2, which was later dehydrated to FAA, and the intramolecularly H-bonded conformer P1 is stable.

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Detailed mechanism and kinetics of reactions of anti- and syn-CH₃CHOO with HC(O)OH: infrared spectra of conformers of hydroperoxyethyl formate

Abstract: We observed IR absorption of three conformers of HPEF from CH3CHOO + HC(O)OH. The open-form conformers P2/P3 rapidly convert to P2, which was later dehydrated to FAA, and the intramolecularly H-bonded conformer P1 is stable.

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References 74 publications

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Detailed mechanism and kinetics of reactions of anti- and syn-CH3CHOO with HC(O)OH: infrared spectra of conformers of hydroperoxyethyl formate

Abstract: We observed IR absorption of three conformers of HPEF from CH3CHOO + HC(O)OH. The open-form conformers P2*/P3* rapidly convert to P2, which was later dehydrated to FAA, and the intramolecularly H-bonded conformer P1 is stable.

Cited by 0 publications

References 74 publications

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Detailed mechanism and kinetics of reactions of anti- and syn-CH₃CHOO with HC(O)OH: infrared spectra of conformers of hydroperoxyethyl formate

Abstract: We observed IR absorption of three conformers of HPEF from CH3CHOO + HC(O)OH. The open-form conformers P2/P3 rapidly convert to P2, which was later dehydrated to FAA, and the intramolecularly H-bonded conformer P1 is stable.