The purchase decisions of customers are influenced by the relevant reviews made by customers. Deceptive reviews are confusing and hard to detect. The existing identification method of deceptive reviews is based on the traditional algorithm of machine learning. However, the methods used to identify deceptive reviews must be improved. In order to improve the accuracy of the identification of deceptive reviews, a novel method integrating sentimental analysis and the characteristics of reviewers was proposed in this study. On the basis of the analysis of the emotional characteristics of the review texts and the behavioural characteristics of the reviewers, a method of deceptive review identification was established. The proposed method analyzed the intensity of emotions, the text similarity, the largest daily publishing comment index, and the extreme rating index on the basis of the feature-weighted model. This model verified the effectiveness of the proposed method. Results show that a direct correlation exists between the unreliability score of users and deceptive review identification. If the score exceeds 0.78, then the reviewer is deemed to be a deceptive reviewer, and the reviews made are deceptive reviews. The proposed method provides a good prospect to identify deceptive reviews.