In this paper, we consider the inverse Robin transmission problem with one electrostatic measurement. We prove a uniqueness result for the simultaneous determination of the Robin parameter p, the conductivity k, and the subdomain D, when D is a ball. When D and k are fixed, we prove a uniqueness result and a directional Lipschitz stability estimate for the Robin parameter p. When p and k are fixed, we give an upper bound to the subdomain D. For the reconstruction purposes of the Robin parameter p, we set the inverse problem under an optimization form for a Kohn-Vogelius cost functional. We prove the existence and the stability of the optimization problem. Finally, we show some numerical experiments that agree with the theoretical considerations.