“…Virtually all explosives currently used for the above purposes contain ammonium nitrate, nitric acid esters or nitrocompounds. Despite their widespread use in blasting operations, such EXs are burdened by significant drawbacks, the most significant of which are the following: - Manufacture from non-renewable resources via highly energy-intensive processes;
- Significant threat to human health and to the environment in the case of nitric acid esters and nitrocompounds [ 7 , 8 , 9 , 10 , 11 ];
- Emission of large amounts of toxic and highly corrosive gases (carbon monoxide, nitrogen oxides) upon detonation [ 12 ];
- Gradual decomposition, particularly in the case of liquid nitric acid esters, as well as gradual leakage of liquid nitroesters from the explosives, necessitating the use of stabilising and anti-leakage agents;
- Susceptibility to misfires (primarily in the case of explosives based on ammonium nitrate)—currently one of the primary threats associated with blasting operations [ 13 , 14 ];
- Susceptibility to theft and subsequent criminal misuse, due to maintaining the ability to detonate even following improper storage or a misfire during blasting [ 15 ];
- Significant risk of fire/explosion during production, transport and disposal, due to susceptibility to undergo detonation caused by various stimuli (e.g., impact, friction) [ 16 , 17 , 18 ];
…”