Arrowhead matrices have attracted attention due to their rich algebraic structures and numerous applications. In this paper, we focus on the enumeration of n × n arrowhead matrices with prescribed determinant over a finite field Fq and over a finite commutative chain ring R. The number of n × n arrowhead matrices over Fq of a fixed determinant a is determined for all positiveintegers n and for all elements a ∈ Fq. As applications, this result is used in the enumeration of n × n non-singular arrowhead matrices with prescribed determinant over R. Subsequently, some bounds on the number of n × n singular arrowhead matrices over R of a fixed determinant are given. Finally, some open problems are presented.