Determination of 1,3-Dichloropropene Degradates in Water and Soil by Capillary Gas Chromatography with Mass Spectrometric Detection

Duebelbeis, Dennis O.; Thomas, Aurélien; Fisher, Stefanie; Schelle, Gary E.

doi:10.1021/bk-1997-0652.ch017

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Development Of Methyl Bromide Replacement Candidates1

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2005

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“…The degradates of 1,3‐D, 3‐chloroallylic alcohols, and 3‐chloroacrylic acids can be analyzed in soil and water extracts by GC‐MS of the corresponding N ‐methyl‐ N ‐( t ‐butyl dimethyl silyl)trifluoroacetamide derivates 83…”

Section: Development Of Methyl Bromide Replacement Candidatesmentioning

confidence: 99%

Physical, chemical and environmental properties of selected chemical alternatives for the pre‐plant use of methyl bromide as soil fumigant

Ruzo

2005

Pest Management Science

116

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Production and use of methyl bromide, a soil fumigant, are being restricted because of this chemical's deleterious effects on stratospheric ozone concentrations. Several products, some of which are currently used as soil fumigants, are being considered as possible replacements for methyl bromide, alone and in various combinations. Among these, 1,3-dichloropropene, methyl isothiocyanate generators such as metam-sodium, and chloropicrin are currently registered, while others such as methyl iodide and sodium azide are at different stages of the registration process. This review examines physicochemical properties, environmental fate, and metabolism of the various potential methyl bromide replacement products.

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Section: Development Of Methyl Bromide Replacement Candidatesmentioning

confidence: 99%