Determination of 90Sr and 210Pb in freshwater fish in Austria

Landstetter, Claudia; Sinojmeri, Merita; Katzlberger, Christian; Achatz, Arno

doi:10.1007/s10967-013-2700-y

Cited by 6 publications

(3 citation statements)

References 4 publications

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“…Results proved that this MSFIA-LOV-ICP-MS method can be used to determine concentrations of lead and strontium in a wide concentration range including trace levels with a high and remarkable reproducibility, together with low consumption of Sr-resin, long lifetime of the column, and good recoveries. In addition, different stages of elution were avoided and the cleanup of the sample was carried out in a single step in comparison with previously developed methods in which Sr-resin was also exploited for the isolation of lead and strontium. ,− Ammonium oxalate had been previously reported in bibliography for lead elution and experimentally, we found that both Sr and Pb can be simultaneously eluted avoiding separation steps when exploiting a selective detector, such as ICP-MS.…”

Section: Resultsmentioning

confidence: 87%

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)

Beltrán

Avivar²,

Mola

et al. 2013

Environ. Sci. Technol.

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A new automated, sensitive, and fast system for the simultaneous online isolation and preconcentration of lead and strontium by sorption on a microcolumn packed with Sr-resin using an inductively coupled plasma mass spectrometry (ICP-MS) detector was developed, hyphenating lab-on-valve (LOV) and multisyringe flow injection analysis (MSFIA). Pb and Sr are directly retained on the sorbent column and eluted with a solution of 0.05 mol L–1 ammonium oxalate. The detection limits achieved were 0.04 ng for lead and 0.03 ng for strontium. Mass calibration curves were used since the proposed system allows the use of different sample volumes for preconcentration. Mass linear working ranges were between 0.13 and 50 ng and 0.1 and 50 ng for lead and strontium, respectively. The repeatability of the method, expressed as RSD, was 2.1% and 2.7% for Pb and Sr, respectively. Environmental samples such as rainwater and airborne particulate (PM10) filters as well as a certified reference material SLRS-4 (river water) were satisfactorily analyzed obtaining recoveries between 90 and 110% for both elements. The main features of the LOV-MSFIA-ICP-MS system proposed are the capability to renew solid phase extraction at will in a fully automated way, the remarkable stability of the column which can be reused up to 160 times, and the potential to perform isotopic analysis.

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Section: Resultsmentioning

confidence: 87%

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)

Beltrán

Avivar²,

Mola

et al. 2013

Environ. Sci. Technol.

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“…In the literature, as can be seen in Table 1, there are a number of Sr resin based strategies that individually separate one of these three radionuclides [8][9][10] or even isolate two of them -e.g. 90 Sr and 210 Pb [11][12][13], 90 Sr and 210 Po [14] or 210 Pb and 210 Po [5,7,[15][16][17][18][19][20][21] -in different kinds of matrices. The table shows the load sample, resin conditioning media and radionuclide elution media used, these being the main parameters that may have an influence on recovery.…”

Section: Introductionmentioning

confidence: 99%

A fast strategy to sequentially separate and determine 90Sr, 210Pb and 210Po in water samples using Sr resin

Martínez

Cobos

Peñalver

et al. 2021

J Radioanal Nucl Chem

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This study presents a rapid and novel sequential separation strategy based on extraction chromatography for determining 90Sr, 210Pb and 210Po in drinking water samples. It involves the use of Sr resin for the separation and then liquid scintillation counting and alpha spectrometry for the determination. The experimental results obtained showed that the proper acidic solution to quantitatively retain the aforementioned radionuclides is 3 M HNO3. The optimum eluents were determined for obtaining quantitative recoveries (70–80%) of 90Sr, 210Pb and 210Po. The method was validated with intercomparison water samples and is satisfactory in terms of minimum detectable activities, which are 50% lower than that established in RD 314/2016.

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“…Different strategies have been investigated for the extraction and pre-concentration of lead in various environmental and biological matrices. Techniques as liquid-liquid extraction (LLE) [9], extraction chromatography (EXC) [10,11] and cloud point extraction (CPE) [12,13] have been reported for this purpose. However, extraction techniques such as LLE or EXC, require the use of significant quantities of organic solvent, which is flammable, volatile, especially toxic and harmful to the environment [14], or substantial volumes of eluents to ensure the complete backextraction of the analyte of interest, respectively.…”

Section: Introductionmentioning

confidence: 99%

Determination of Pb in environmental samples after cloud point extraction using crown ether

Blanchet-Chouinard

Larivière

2018

Talanta

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In the present study, a new cloud point extraction methodology based on the selective preconcentration and the extraction of stable lead in acidic conditions with 4',4''(5'')-di-tert-butyldicyclohexano-18-crown-6 as a chelating agent was developed, optimized and validated. A mixture of Triton X-114 as non-ionic surfactant and CTAB as cationic surfactant was used to produce micellar structures that incorporate the chelating agent. Phase separation, induced by coacervation, was achieved by increasing the temperature of the system above the cloud point temperature. Pb extraction efficiency was maximized through an optimisation process where the effect of each parameter (i.e. non-ionic and ionic surfactant concentrations, pH, chelating agent concentration and cloud point temperature) on the chemical recoveries of Pb was assessed. Under optimum experimental conditions, the method reaches recoveries greater than 67% for Pb in a variety of complex matrices. In order to facilitate the quantification of Pb by plasma based instrumentations, a back-extraction procedure using aqueous solution of ammonium citrate were performed on the surfactant rich phase in order to reduce the effects on sample introduction and non-spectral interferences. LOD and LOQ of 0.8µgL and 2.6µgL, respectively, were determined by ICP-OES for the complete procedure. Using the back-extraction approach, a preconcentration factor of 39 was achieved for an initial sample volume of 195mL. The ruggedness of the methodology was validated by determining Pb concentration in various environmental and biological samples.

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Determination of 90Sr and 210Pb in freshwater fish in Austria

Cited by 6 publications

References 4 publications

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)

A fast strategy to sequentially separate and determine 90Sr, 210Pb and 210Po in water samples using Sr resin

Determination of Pb in environmental samples after cloud point extraction using crown ether

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Determination of 90Sr and 210Pb in freshwater fish in Austria

Cited by 6 publications

References 4 publications

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM10)

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM10)

A fast strategy to sequentially separate and determine 90Sr, 210Pb and 210Po in water samples using Sr resin

Determination of Pb in environmental samples after cloud point extraction using crown ether

Contact Info

Product

Resources

About

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)

Automated Method for Simultaneous Lead and Strontium Isotopic Analysis Applied to Rainwater Samples and Airborne Particulate Filters (PM₁₀)