Determination of Air–Fuel Ratio at 1 kHz via Mid-Infrared Laser Absorption and Fast Flame Ionization Detector Measurements in Engine-Out Vehicle Exhaust

Abstract

<div>Measurements of air–fuel ratio (AFR) and <i>λ</i> (AFR<sub>actual</sub>/AFR<sub>stoich</sub>) are crucial for understanding internal combustion engine (ICE) performance. However, current <i>λ</i> sensors suffer from long light-off times (on the order of seconds following a cold start) and limited time resolution. In this study, a four-color mid-infrared laser absorption spectroscopy (LAS) sensor was developed to provide 5 kHz measurements of temperature, CO, CO<sub>2</sub>, and NO in engine-out exhaust. This LAS sensor was then combined with 1 kHz hydrocarbon (HC) measurements from a flame ionization detector (FID), and the Spindt exhaust gas analysis method to provide 1 kHz measurements of <i>λ</i>. To the authors’ knowledge, this is the first time-resolved measurement of <i>λ</i> during engine cold starts using the full Spindt method. Three tests with various engine AFR calibrations were conducted and analyzed: (1) 10% lean, (2) stoichiometric, and (3) 10% rich. The measurements were acquired in the exhaust of a light-duty truck with an 8-cylinder gasoline engine. The LAS-FID-based <i>λ</i> sensor results were compared with those obtained from a universal exhaust gas oxygen (UEGO) sensor. The LAS-FID method provided robust <i>λ</i> measurements from the first combustion exhaust event (avoiding the light-off time associated with traditional <i>λ</i> sensors) in addition to enhanced temporal resolution (on the order of 100× increase compared to traditional diffusion-based <i>λ</i> sensors). The insight gained from this novel method could be used to benefit crank, cold start, and open- or closed-loop air–fuel ratio control strategies in gasoline engines for reduced emissions.</div>