Determination of benzothiazoles from complex aqueous samples by liquid chromatography–mass spectrometry following solid-phase extraction

Kloepfer, Achim; Jekel, Martin; Reemtsma, Thorsten

doi:10.1016/j.chroma.2004.08.081

Cited by 45 publications

(20 citation statements)

References 21 publications

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“…Further emissions may stem from the use of benzothiazole-containing consumer products like rubber materials (tires and shoes). The 1H-benzotriazoles and benzothiazoles are soluble in water, resistant to biodegradation, only partially removed in wastewater treatment [1,2,3,4], and they may pass the water treatment processes employed in the production of drinking water.…”

Section: E-mail Address: Tonvanleerdam@kwrwaternl (Ja Van Leerdam)mentioning

confidence: 99%

“…Giger et al developed a LC-MS-MS method, using Oasis HLB SPE cartridges for extraction and concentration [5]. Kloepfer et al [2,3] used a SPE-LC-MS method and showed that benzothiazoles are present in samples from both the influent and effluent of municipal wastewater treatment plants (WWTP) in Berlin and are thus not completely removed in the wastewater treatment. Weiss and Reemtsma [1] conclude the same for 1H-benzotriazoles found in wastewater and surface water in the Berlin region.…”

Section: E-mail Address: Tonvanleerdam@kwrwaternl (Ja Van Leerdam)mentioning

confidence: 99%

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Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

Leerdam

Hogenboom

Kooi

et al. 2009

International Journal of Mass Spectrometry

104

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Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry van Leerdam, J.A.; Hogenboom, A.C.; van der Kooi, M.M.E.; de Voogt, W.P. General rightsIt is not permitted to download or to forward/distribute the text or part of it without the consent of the author(s) and/or copyright holder(s), other than for strictly personal, individual use, unless the work is under an open content license (like Creative Commons). Disclaimer/Complaints regulationsIf you believe that digital publication of certain material infringes any of your rights or (privacy) interests, please let the Library know, stating your reasons. In case of a legitimate complaint, the Library will make the material inaccessible and/or remove it from the website. Please Ask the Library: https://uba.uva.nl/en/contact, or a letter to: Library of the University of Amsterdam, Secretariat, Singel 425, 1012 WP Amsterdam, The Netherlands. You will be contacted as soon as possible. Download date: 22 Jun 2019This article appeared in a journal published by Elsevier. The attached copy is furnished to the author for internal non-commercial research and education use, including for instruction at the authors institution and sharing with colleagues.Other uses, including reproduction and distribution, or selling or licensing copies, or posting to personal, institutional or third party websites are prohibited. a b s t r a c tA sensitive, reliable and robust method for the trace determination of six polar 1H-benzotriazoles and four benzothiazoles in drinking and surface water was developed. These compounds were extracted from water by solid-phase extraction and analyzed by Liquid Chromatography-Electrospray Mass Spectrometry using a linear ion trap-Orbitrap hybrid instrument at high resolution of 30,000 FWHM in the full-scan acquisition mode. At least one product ion was simultaneously detected in the linear ion trap at low mass resolution and was used for confirmation of compound identity. The compounds studied are soluble in water, resistant to biodegradation, only partially removed in wastewater treatment and they may pass the water treatment processes in the production of drinking water.The analytes and four internal standards were preconcentrated by solid-phase extraction at low pH. Positive electrospray ionization resulted in protonated molecular ions for all the 1H-benzotriazoles and benzothiazoles.The mass accuracy was between −5 ppm at m/z 120 and −0.1 ppm at m/z 182 and did not change for more than 2 ppm over a sample sequence of 8 days of analysis time. The optimized method allowed quantifying six benzotriazoles and four benzothiazoles in samples of drinking and surface water down to method detection limits of 0.01 g/L. The recoveries ranged between 45 and 125% in ultrapure, drinking and surface water at a spiking level of 0.2 g/L; the repeatability was between 2 and 13%. All analytes showed a linear response between 0.01 and 1.0 g/L. No significant matrix effect w...

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Section: E-mail Address: Tonvanleerdam@kwrwaternl (Ja Van Leerdam)mentioning

confidence: 99%

Section: E-mail Address: Tonvanleerdam@kwrwaternl (Ja Van Leerdam)mentioning

confidence: 99%

Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

Leerdam

Hogenboom

Kooi

et al. 2009

International Journal of Mass Spectrometry

104

View full text Add to dashboard Cite

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“…[7][8][9][10] Benzothiazole is an organic compound used as accelerators for the vulcanization of rubbers, as an insecticide, in the production of dyes and pharmaceutical drugs and as a food-°avoring agent. 11 The corrosion inhibition properties of benzothiazole derivatives have been proven to be e®ective in previous studies on carbon steel in HCl solution, copper in neutral chloride solutions and austenitic stainless steel (type 304). [12][13][14] 410 martensitic stainless steel is applied in petroleum fractionating structures, mine ladder rungs, gas turbines, shafts, pumps, valves and as bolts, screws, bushings and nuts.…”

Section: Introductionmentioning

confidence: 99%

ANTI-CORROSION PERFORMANCE OF 1,3-BENZOTHIAZOLE ON 410 MARTENSITIC STAINLESS STEEL IN H₂SO₄

Loto

2017

Surf. Rev. Lett.

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The corrosion inhibition e®ect of synthesized 1,3-benzothiazole at very low concentrations on 410 martensitic stainless steel in 3 MH 2 SO 4 solution was studied through potentiodynamic polarization and weight loss measurements. The observation showed that the organic compound performed e®ectively with average inhibition e±ciencies of 94% and 98% at the concentrations studied from both electrochemical methods due to the inhibition action of protonated inhibitor molecules in the acid solution. The amine and aromatics functional groups of the molecules active in the corrosion inhibition reaction were exposed from Attenuated total re°ectance-Fourier transform infrared spectroscopy (ATR-FTIR) spectroscopic analysis. Thermodynamic calculations showed cationic adsorption to be chemisorption adsorption, obeying the Langmuir adsorption isotherm. Images from optical microscopy showed an improved morphology in comparison to images from corroded stainless steel. Severe surface deterioration and macro-pits were observed in the uninhibited samples.

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“…Of these materials, the Oasis HLB product appears to be the most extensively used sorbent for the extraction of polar compounds and especially acidic compounds, like herbicides [64], disinfection by-products [65], and acidic drugs [66,67]. It has also been employed for the SPE of neutral compounds like phosphoric acid triesters [68], weakly acidic analytes (e.g., triclosan [26,27]), 9 and for the simultaneous extraction of acidic and basic compounds like benzothiazoles and benzotriazoles [69,70]. In a recent study, several SPE sorbents were tested for the simultaneous extraction of acidic, neutral, and basic drugs, and Oasis HLB proved to provide the best recoveries even at pH 7.8, thus avoiding the acidification step often necessary for the determination of acidic compounds with C-18 cartridges [71].…”

Section: For Basic/cationic Analytesmentioning

confidence: 99%

“…If quaternary ammonium compounds become more polar, and retention in RPLC is difficult to obtain, IP-RPLC can be used (see above). Aromatic nitrogenous compounds like benzothiazoles [69,171] and benzotriazoles [70] can be analyzed with ammonium acetate using ESI in positive mode. The same approach is used for basic pharmaceuticals such as â-2-sympathomimetics and beta-blockers [10,48,158].…”

Section: Weakly Basic Compoundsmentioning

confidence: 99%

Analytical Methods for Polar Pollutants

Reemtsma

Quintana

2006

Organic Pollutants in the Water Cycle

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Determination of benzothiazoles from complex aqueous samples by liquid chromatography–mass spectrometry following solid-phase extraction

Cited by 45 publications

References 21 publications

Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

ANTI-CORROSION PERFORMANCE OF 1,3-BENZOTHIAZOLE ON 410 MARTENSITIC STAINLESS STEEL IN H₂SO₄

Analytical Methods for Polar Pollutants

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Determination of benzothiazoles from complex aqueous samples by liquid chromatography–mass spectrometry following solid-phase extraction

Cited by 45 publications

References 21 publications

Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

Determination of polar 1H-benzotriazoles and benzothiazoles in water by solid-phase extraction and liquid chromatography LTQ FT Orbitrap mass spectrometry

ANTI-CORROSION PERFORMANCE OF 1,3-BENZOTHIAZOLE ON 410 MARTENSITIC STAINLESS STEEL IN H2SO4

Analytical Methods for Polar Pollutants

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ANTI-CORROSION PERFORMANCE OF 1,3-BENZOTHIAZOLE ON 410 MARTENSITIC STAINLESS STEEL IN H₂SO₄